Protactinium and the intersection of actinide and transition metal chemistry

The role of the 5f and 6d orbitals in the chemical bonding of the actinide elements remains debated. Here, the authors synthesize and study a tetranuclear protactinium peroxo cluster and demonstrate that protactinium represents an intersection of actinide (5f) and transition metal (6d) chemistries.

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Detalles Bibliográficos
Autores principales:	Richard E. Wilson, Stephanie De Sio, Valérie Vallet
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/75bbabf87f174f84be70ec0913eac76c
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id	oai:doaj.org-article:75bbabf87f174f84be70ec0913eac76c
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spelling	oai:doaj.org-article:75bbabf87f174f84be70ec0913eac76c2021-12-02T15:33:34ZProtactinium and the intersection of actinide and transition metal chemistry10.1038/s41467-018-02972-z2041-1723https://doaj.org/article/75bbabf87f174f84be70ec0913eac76c2018-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-02972-zhttps://doaj.org/toc/2041-1723The role of the 5f and 6d orbitals in the chemical bonding of the actinide elements remains debated. Here, the authors synthesize and study a tetranuclear protactinium peroxo cluster and demonstrate that protactinium represents an intersection of actinide (5f) and transition metal (6d) chemistries.Richard E. WilsonStephanie De SioValérie ValletNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Richard E. Wilson Stephanie De Sio Valérie Vallet Protactinium and the intersection of actinide and transition metal chemistry
description	The role of the 5f and 6d orbitals in the chemical bonding of the actinide elements remains debated. Here, the authors synthesize and study a tetranuclear protactinium peroxo cluster and demonstrate that protactinium represents an intersection of actinide (5f) and transition metal (6d) chemistries.
format	article
author	Richard E. Wilson Stephanie De Sio Valérie Vallet
author_facet	Richard E. Wilson Stephanie De Sio Valérie Vallet
author_sort	Richard E. Wilson
title	Protactinium and the intersection of actinide and transition metal chemistry
title_short	Protactinium and the intersection of actinide and transition metal chemistry
title_full	Protactinium and the intersection of actinide and transition metal chemistry
title_fullStr	Protactinium and the intersection of actinide and transition metal chemistry
title_full_unstemmed	Protactinium and the intersection of actinide and transition metal chemistry
title_sort	protactinium and the intersection of actinide and transition metal chemistry
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/75bbabf87f174f84be70ec0913eac76c
work_keys_str_mv	AT richardewilson protactiniumandtheintersectionofactinideandtransitionmetalchemistry AT stephaniedesio protactiniumandtheintersectionofactinideandtransitionmetalchemistry AT valerievallet protactiniumandtheintersectionofactinideandtransitionmetalchemistry
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Protactinium and the intersection of actinide and transition metal chemistry

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