Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis

Phosphonyl and carboxyl groups are valuable functional groups, however their simultaneous incorporation via catalytic difunctionalization of alkenes has not been realized yet. Here the authors report the phosphonocarboxylation of alkenes with CO2 via visible-light photoredox catalysis.

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Autores principales:	Qiang Fu, Zhi-Yu Bo, Jian-Heng Ye, Tao Ju, He Huang, Li-Li Liao, Da-Gang Yu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/75e6e53c912b4d1dac7a1c83c2c6ee58
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spelling	oai:doaj.org-article:75e6e53c912b4d1dac7a1c83c2c6ee582021-12-02T15:36:21ZTransition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis10.1038/s41467-019-11528-82041-1723https://doaj.org/article/75e6e53c912b4d1dac7a1c83c2c6ee582019-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11528-8https://doaj.org/toc/2041-1723Phosphonyl and carboxyl groups are valuable functional groups, however their simultaneous incorporation via catalytic difunctionalization of alkenes has not been realized yet. Here the authors report the phosphonocarboxylation of alkenes with CO2 via visible-light photoredox catalysis.Qiang FuZhi-Yu BoJian-Heng YeTao JuHe HuangLi-Li LiaoDa-Gang YuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Qiang Fu Zhi-Yu Bo Jian-Heng Ye Tao Ju He Huang Li-Li Liao Da-Gang Yu Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis
description	Phosphonyl and carboxyl groups are valuable functional groups, however their simultaneous incorporation via catalytic difunctionalization of alkenes has not been realized yet. Here the authors report the phosphonocarboxylation of alkenes with CO2 via visible-light photoredox catalysis.
format	article
author	Qiang Fu Zhi-Yu Bo Jian-Heng Ye Tao Ju He Huang Li-Li Liao Da-Gang Yu
author_facet	Qiang Fu Zhi-Yu Bo Jian-Heng Ye Tao Ju He Huang Li-Li Liao Da-Gang Yu
author_sort	Qiang Fu
title	Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis
title_short	Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis
title_full	Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis
title_fullStr	Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis
title_full_unstemmed	Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis
title_sort	transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/75e6e53c912b4d1dac7a1c83c2c6ee58
work_keys_str_mv	AT qiangfu transitionmetalfreephosphonocarboxylationofalkeneswithcarbondioxideviavisiblelightphotoredoxcatalysis AT zhiyubo transitionmetalfreephosphonocarboxylationofalkeneswithcarbondioxideviavisiblelightphotoredoxcatalysis AT jianhengye transitionmetalfreephosphonocarboxylationofalkeneswithcarbondioxideviavisiblelightphotoredoxcatalysis AT taoju transitionmetalfreephosphonocarboxylationofalkeneswithcarbondioxideviavisiblelightphotoredoxcatalysis AT hehuang transitionmetalfreephosphonocarboxylationofalkeneswithcarbondioxideviavisiblelightphotoredoxcatalysis AT lililiao transitionmetalfreephosphonocarboxylationofalkeneswithcarbondioxideviavisiblelightphotoredoxcatalysis AT dagangyu transitionmetalfreephosphonocarboxylationofalkeneswithcarbondioxideviavisiblelightphotoredoxcatalysis
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Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis

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