Nanoscale π–π stacked molecules are bound by collective charge fluctuations

Attractive, non-covalent interactions between aromatic rings—termedπ−πstacking—is common in chemistry but difficult to model. Here the authors report a quantum-mechanical model to show the importance of collective charge fluctuations for understanding pi-stacked supramolecular systems.

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Detalles Bibliográficos
Autores principales: Jan Hermann, Dario Alfè, Alexandre Tkatchenko
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
Materias:
Q
Acceso en línea:https://doaj.org/article/764e0b72d8f84332958c25841f9ce2be
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