Production and Characterization of Polyethylene Terephthalate Nanoparticles

Microplastic (MP) pollution represents one of the biggest environmental problems that is further exacerbated by the continuous degradation in the marine environment of MPs to nanoplastics (NPs). The most diffuse plastics in oceans are commodity polymers, mainly thermoplastics widely used for packagi...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Francesca Lionetto, Carola Esposito Corcione, Aurora Rizzo, Alfonso Maffezzoli
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
Materias:
DSC
Acceso en línea:https://doaj.org/article/765c1bb94c3944c6804bd636e1c0b584
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:765c1bb94c3944c6804bd636e1c0b584
record_format dspace
spelling oai:doaj.org-article:765c1bb94c3944c6804bd636e1c0b5842021-11-11T18:46:11ZProduction and Characterization of Polyethylene Terephthalate Nanoparticles10.3390/polym132137452073-4360https://doaj.org/article/765c1bb94c3944c6804bd636e1c0b5842021-10-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/21/3745https://doaj.org/toc/2073-4360Microplastic (MP) pollution represents one of the biggest environmental problems that is further exacerbated by the continuous degradation in the marine environment of MPs to nanoplastics (NPs). The most diffuse plastics in oceans are commodity polymers, mainly thermoplastics widely used for packaging, such as polyethylene terephthalate (PET). However, the huge interest in the chemical vector role of micro/nanoplastics, their fate and negative effects on the environment and human health is still under discussion and the research is still sparse due also to the difficulties of sampling MPs and NPs from the environment or producing NPs in laboratory. Moreover, the research on MPs and NPs pollution relies on the availability of engineered nanoparticles similar to those present in the marine environment for toxicological, transport and adsorption studies in biological tissues as well as for wastewater remediation studies. This work aims to develop an easy, fast and scalable procedure for the production of representative model nanoplastics from PET pellets. The proposed method, based on a simple and economic milling process, has been optimized considering the peculiarities of the polymer. The results demonstrated the reliability of the method for preparing particle suspensions for aquatic microplastic research, with evident advantages compared to the present literature procedures, such as low cost, the absence of liquid nitrogen, the short production time, the high yield of the process, stability, reproducibility and polydisperse size distribution of the produced water dispersed nanometric PET.Francesca LionettoCarola Esposito CorcioneAurora RizzoAlfonso MaffezzoliMDPI AGarticlepoly (ethylene terephthalate) nanoplasticsmodel nanoplasticsmicroplasticsannealingDSCmarine plasticsOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3745, p 3745 (2021)
institution DOAJ
collection DOAJ
language EN
topic poly (ethylene terephthalate) nanoplastics
model nanoplastics
microplastics
annealing
DSC
marine plastics
Organic chemistry
QD241-441
spellingShingle poly (ethylene terephthalate) nanoplastics
model nanoplastics
microplastics
annealing
DSC
marine plastics
Organic chemistry
QD241-441
Francesca Lionetto
Carola Esposito Corcione
Aurora Rizzo
Alfonso Maffezzoli
Production and Characterization of Polyethylene Terephthalate Nanoparticles
description Microplastic (MP) pollution represents one of the biggest environmental problems that is further exacerbated by the continuous degradation in the marine environment of MPs to nanoplastics (NPs). The most diffuse plastics in oceans are commodity polymers, mainly thermoplastics widely used for packaging, such as polyethylene terephthalate (PET). However, the huge interest in the chemical vector role of micro/nanoplastics, their fate and negative effects on the environment and human health is still under discussion and the research is still sparse due also to the difficulties of sampling MPs and NPs from the environment or producing NPs in laboratory. Moreover, the research on MPs and NPs pollution relies on the availability of engineered nanoparticles similar to those present in the marine environment for toxicological, transport and adsorption studies in biological tissues as well as for wastewater remediation studies. This work aims to develop an easy, fast and scalable procedure for the production of representative model nanoplastics from PET pellets. The proposed method, based on a simple and economic milling process, has been optimized considering the peculiarities of the polymer. The results demonstrated the reliability of the method for preparing particle suspensions for aquatic microplastic research, with evident advantages compared to the present literature procedures, such as low cost, the absence of liquid nitrogen, the short production time, the high yield of the process, stability, reproducibility and polydisperse size distribution of the produced water dispersed nanometric PET.
format article
author Francesca Lionetto
Carola Esposito Corcione
Aurora Rizzo
Alfonso Maffezzoli
author_facet Francesca Lionetto
Carola Esposito Corcione
Aurora Rizzo
Alfonso Maffezzoli
author_sort Francesca Lionetto
title Production and Characterization of Polyethylene Terephthalate Nanoparticles
title_short Production and Characterization of Polyethylene Terephthalate Nanoparticles
title_full Production and Characterization of Polyethylene Terephthalate Nanoparticles
title_fullStr Production and Characterization of Polyethylene Terephthalate Nanoparticles
title_full_unstemmed Production and Characterization of Polyethylene Terephthalate Nanoparticles
title_sort production and characterization of polyethylene terephthalate nanoparticles
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/765c1bb94c3944c6804bd636e1c0b584
work_keys_str_mv AT francescalionetto productionandcharacterizationofpolyethyleneterephthalatenanoparticles
AT carolaespositocorcione productionandcharacterizationofpolyethyleneterephthalatenanoparticles
AT aurorarizzo productionandcharacterizationofpolyethyleneterephthalatenanoparticles
AT alfonsomaffezzoli productionandcharacterizationofpolyethyleneterephthalatenanoparticles
_version_ 1718431709297377280