Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions

A sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox conditions.

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Detalles Bibliográficos
Autores principales: Guoting Zhang, Yulin Lin, Xu Luo, Xia Hu, Cong Chen, Aiwen Lei
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/76c312ca639a4aee88981fedfed99abc
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Sumario:A sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox conditions.