Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions

A sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox conditions.

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Autores principales:	Guoting Zhang, Yulin Lin, Xu Luo, Xia Hu, Cong Chen, Aiwen Lei
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/76c312ca639a4aee88981fedfed99abc
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spelling	oai:doaj.org-article:76c312ca639a4aee88981fedfed99abc2021-12-02T15:33:45ZOxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions10.1038/s41467-018-03534-z2041-1723https://doaj.org/article/76c312ca639a4aee88981fedfed99abc2018-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-03534-zhttps://doaj.org/toc/2041-1723A sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox conditions.Guoting ZhangYulin LinXu LuoXia HuCong ChenAiwen LeiNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Guoting Zhang Yulin Lin Xu Luo Xia Hu Cong Chen Aiwen Lei Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions
description	A sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox conditions.
format	article
author	Guoting Zhang Yulin Lin Xu Luo Xia Hu Cong Chen Aiwen Lei
author_facet	Guoting Zhang Yulin Lin Xu Luo Xia Hu Cong Chen Aiwen Lei
author_sort	Guoting Zhang
title	Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions
title_short	Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions
title_full	Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions
title_fullStr	Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions
title_full_unstemmed	Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions
title_sort	oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/76c312ca639a4aee88981fedfed99abc
work_keys_str_mv	AT guotingzhang oxidative42annulationofstyreneswithalkynesunderexternaloxidantfreeconditions AT yulinlin oxidative42annulationofstyreneswithalkynesunderexternaloxidantfreeconditions AT xuluo oxidative42annulationofstyreneswithalkynesunderexternaloxidantfreeconditions AT xiahu oxidative42annulationofstyreneswithalkynesunderexternaloxidantfreeconditions AT congchen oxidative42annulationofstyreneswithalkynesunderexternaloxidantfreeconditions AT aiwenlei oxidative42annulationofstyreneswithalkynesunderexternaloxidantfreeconditions
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Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions

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