Zinc-Doped Titania Embedded on the Surface of Zirconia: A Potential Visible-Responsive Photocatalyst Material

The preparation and characterization of zirconia-supported titania with a zinc dopant had been studied. Zinc-doped titania was grown on the surface of zirconia by the sol-gel method. Various zinc contents and calcination temperatures were applied to investigate the zinc doping effect and crystal str...

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Autores principales: Azizia Alifi, Rian Kurniawan, Akhmad Syoufian
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Publicado: Department of Chemistry, Universitas Gadjah Mada 2020
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spelling oai:doaj.org-article:770ef432b3574abcbf4f8a094fa681362021-12-02T12:53:43ZZinc-Doped Titania Embedded on the Surface of Zirconia: A Potential Visible-Responsive Photocatalyst Material1411-94202460-157810.22146/ijc.51172https://doaj.org/article/770ef432b3574abcbf4f8a094fa681362020-04-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/51172https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578The preparation and characterization of zirconia-supported titania with a zinc dopant had been studied. Zinc-doped titania was grown on the surface of zirconia by the sol-gel method. Various zinc contents and calcination temperatures were applied to investigate the zinc doping effect and crystal structure of the zirconia-titania composite. X-ray diffraction method, Fourier-transform infrared spectroscopy, and UV-Vis reflectance spectroscopy were performed to characterize the composite. The morphology of the composite was observed by using a scanning electron microscope, and its composition was analyzed by using energy dispersive spectroscopy. Among various zinc dopant contents and calcination temperatures investigated, doping with 5% zinc (Zn wt./Ti wt.) at 900 °C calcination shows the best result in response to visible light with a bandgap of 2.87 eV and absorption edge wavelength of 432.61 nm.Azizia AlifiRian KurniawanAkhmad SyoufianDepartment of Chemistry, Universitas Gadjah Madaarticletitaniazinczirconiasol-geldopingChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 20, Iss 6, Pp 1374-1381 (2020)
institution DOAJ
collection DOAJ
language EN
topic titania
zinc
zirconia
sol-gel
doping
Chemistry
QD1-999
spellingShingle titania
zinc
zirconia
sol-gel
doping
Chemistry
QD1-999
Azizia Alifi
Rian Kurniawan
Akhmad Syoufian
Zinc-Doped Titania Embedded on the Surface of Zirconia: A Potential Visible-Responsive Photocatalyst Material
description The preparation and characterization of zirconia-supported titania with a zinc dopant had been studied. Zinc-doped titania was grown on the surface of zirconia by the sol-gel method. Various zinc contents and calcination temperatures were applied to investigate the zinc doping effect and crystal structure of the zirconia-titania composite. X-ray diffraction method, Fourier-transform infrared spectroscopy, and UV-Vis reflectance spectroscopy were performed to characterize the composite. The morphology of the composite was observed by using a scanning electron microscope, and its composition was analyzed by using energy dispersive spectroscopy. Among various zinc dopant contents and calcination temperatures investigated, doping with 5% zinc (Zn wt./Ti wt.) at 900 °C calcination shows the best result in response to visible light with a bandgap of 2.87 eV and absorption edge wavelength of 432.61 nm.
format article
author Azizia Alifi
Rian Kurniawan
Akhmad Syoufian
author_facet Azizia Alifi
Rian Kurniawan
Akhmad Syoufian
author_sort Azizia Alifi
title Zinc-Doped Titania Embedded on the Surface of Zirconia: A Potential Visible-Responsive Photocatalyst Material
title_short Zinc-Doped Titania Embedded on the Surface of Zirconia: A Potential Visible-Responsive Photocatalyst Material
title_full Zinc-Doped Titania Embedded on the Surface of Zirconia: A Potential Visible-Responsive Photocatalyst Material
title_fullStr Zinc-Doped Titania Embedded on the Surface of Zirconia: A Potential Visible-Responsive Photocatalyst Material
title_full_unstemmed Zinc-Doped Titania Embedded on the Surface of Zirconia: A Potential Visible-Responsive Photocatalyst Material
title_sort zinc-doped titania embedded on the surface of zirconia: a potential visible-responsive photocatalyst material
publisher Department of Chemistry, Universitas Gadjah Mada
publishDate 2020
url https://doaj.org/article/770ef432b3574abcbf4f8a094fa68136
work_keys_str_mv AT aziziaalifi zincdopedtitaniaembeddedonthesurfaceofzirconiaapotentialvisibleresponsivephotocatalystmaterial
AT riankurniawan zincdopedtitaniaembeddedonthesurfaceofzirconiaapotentialvisibleresponsivephotocatalystmaterial
AT akhmadsyoufian zincdopedtitaniaembeddedonthesurfaceofzirconiaapotentialvisibleresponsivephotocatalystmaterial
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