Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries

Abstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an except...

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Autores principales: Changling Li, Chueh Liu, Wei Wang, Zafer Mutlu, Jeffrey Bell, Kazi Ahmed, Rachel Ye, Mihrimah Ozkan, Cengiz S. Ozkan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/7904b93fc2f74848b6d7c8135f538a6b
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Sumario:Abstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an exceptional anode material towards large-scale energy storage applications, due to its extraordinary lithiation capacity of 3579 mAh g−1 at ambient temperature. Compared with other quartz sources obtained from pre-leaching processes which apply toxic acids and high energy-consuming annealing, an interconnected silicon network is directly derived from glass bottles via magnesiothermic reduction. Carbon-coated glass derived-silicon (gSi@C) electrodes demonstrate excellent electrochemical performance with a capacity of ~1420 mAh g−1 at C/2 after 400 cycles. Full cells consisting of gSi@C anodes and LiCoO2 cathodes are assembled and achieve good initial cycling stability with high energy density.