Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries

Abstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an except...

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Autores principales: Changling Li, Chueh Liu, Wei Wang, Zafer Mutlu, Jeffrey Bell, Kazi Ahmed, Rachel Ye, Mihrimah Ozkan, Cengiz S. Ozkan
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Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/7904b93fc2f74848b6d7c8135f538a6b
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spelling oai:doaj.org-article:7904b93fc2f74848b6d7c8135f538a6b2021-12-02T12:32:19ZSilicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries10.1038/s41598-017-01086-82045-2322https://doaj.org/article/7904b93fc2f74848b6d7c8135f538a6b2017-04-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-01086-8https://doaj.org/toc/2045-2322Abstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an exceptional anode material towards large-scale energy storage applications, due to its extraordinary lithiation capacity of 3579 mAh g−1 at ambient temperature. Compared with other quartz sources obtained from pre-leaching processes which apply toxic acids and high energy-consuming annealing, an interconnected silicon network is directly derived from glass bottles via magnesiothermic reduction. Carbon-coated glass derived-silicon (gSi@C) electrodes demonstrate excellent electrochemical performance with a capacity of ~1420 mAh g−1 at C/2 after 400 cycles. Full cells consisting of gSi@C anodes and LiCoO2 cathodes are assembled and achieve good initial cycling stability with high energy density.Changling LiChueh LiuWei WangZafer MutluJeffrey BellKazi AhmedRachel YeMihrimah OzkanCengiz S. OzkanNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-11 (2017)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Changling Li
Chueh Liu
Wei Wang
Zafer Mutlu
Jeffrey Bell
Kazi Ahmed
Rachel Ye
Mihrimah Ozkan
Cengiz S. Ozkan
Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries
description Abstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an exceptional anode material towards large-scale energy storage applications, due to its extraordinary lithiation capacity of 3579 mAh g−1 at ambient temperature. Compared with other quartz sources obtained from pre-leaching processes which apply toxic acids and high energy-consuming annealing, an interconnected silicon network is directly derived from glass bottles via magnesiothermic reduction. Carbon-coated glass derived-silicon (gSi@C) electrodes demonstrate excellent electrochemical performance with a capacity of ~1420 mAh g−1 at C/2 after 400 cycles. Full cells consisting of gSi@C anodes and LiCoO2 cathodes are assembled and achieve good initial cycling stability with high energy density.
format article
author Changling Li
Chueh Liu
Wei Wang
Zafer Mutlu
Jeffrey Bell
Kazi Ahmed
Rachel Ye
Mihrimah Ozkan
Cengiz S. Ozkan
author_facet Changling Li
Chueh Liu
Wei Wang
Zafer Mutlu
Jeffrey Bell
Kazi Ahmed
Rachel Ye
Mihrimah Ozkan
Cengiz S. Ozkan
author_sort Changling Li
title Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries
title_short Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries
title_full Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries
title_fullStr Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries
title_full_unstemmed Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries
title_sort silicon derived from glass bottles as anode materials for lithium ion full cell batteries
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/7904b93fc2f74848b6d7c8135f538a6b
work_keys_str_mv AT changlingli siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries
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AT weiwang siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries
AT zafermutlu siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries
AT jeffreybell siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries
AT kaziahmed siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries
AT rachelye siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries
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