Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries
Abstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an except...
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2017
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oai:doaj.org-article:7904b93fc2f74848b6d7c8135f538a6b2021-12-02T12:32:19ZSilicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries10.1038/s41598-017-01086-82045-2322https://doaj.org/article/7904b93fc2f74848b6d7c8135f538a6b2017-04-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-01086-8https://doaj.org/toc/2045-2322Abstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an exceptional anode material towards large-scale energy storage applications, due to its extraordinary lithiation capacity of 3579 mAh g−1 at ambient temperature. Compared with other quartz sources obtained from pre-leaching processes which apply toxic acids and high energy-consuming annealing, an interconnected silicon network is directly derived from glass bottles via magnesiothermic reduction. Carbon-coated glass derived-silicon (gSi@C) electrodes demonstrate excellent electrochemical performance with a capacity of ~1420 mAh g−1 at C/2 after 400 cycles. Full cells consisting of gSi@C anodes and LiCoO2 cathodes are assembled and achieve good initial cycling stability with high energy density.Changling LiChueh LiuWei WangZafer MutluJeffrey BellKazi AhmedRachel YeMihrimah OzkanCengiz S. OzkanNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-11 (2017) |
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Medicine R Science Q Changling Li Chueh Liu Wei Wang Zafer Mutlu Jeffrey Bell Kazi Ahmed Rachel Ye Mihrimah Ozkan Cengiz S. Ozkan Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
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Abstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an exceptional anode material towards large-scale energy storage applications, due to its extraordinary lithiation capacity of 3579 mAh g−1 at ambient temperature. Compared with other quartz sources obtained from pre-leaching processes which apply toxic acids and high energy-consuming annealing, an interconnected silicon network is directly derived from glass bottles via magnesiothermic reduction. Carbon-coated glass derived-silicon (gSi@C) electrodes demonstrate excellent electrochemical performance with a capacity of ~1420 mAh g−1 at C/2 after 400 cycles. Full cells consisting of gSi@C anodes and LiCoO2 cathodes are assembled and achieve good initial cycling stability with high energy density. |
format |
article |
author |
Changling Li Chueh Liu Wei Wang Zafer Mutlu Jeffrey Bell Kazi Ahmed Rachel Ye Mihrimah Ozkan Cengiz S. Ozkan |
author_facet |
Changling Li Chueh Liu Wei Wang Zafer Mutlu Jeffrey Bell Kazi Ahmed Rachel Ye Mihrimah Ozkan Cengiz S. Ozkan |
author_sort |
Changling Li |
title |
Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
title_short |
Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
title_full |
Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
title_fullStr |
Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
title_full_unstemmed |
Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
title_sort |
silicon derived from glass bottles as anode materials for lithium ion full cell batteries |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/7904b93fc2f74848b6d7c8135f538a6b |
work_keys_str_mv |
AT changlingli siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries AT chuehliu siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries AT weiwang siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries AT zafermutlu siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries AT jeffreybell siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries AT kaziahmed siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries AT rachelye siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries AT mihrimahozkan siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries AT cengizsozkan siliconderivedfromglassbottlesasanodematerialsforlithiumionfullcellbatteries |
_version_ |
1718394102654959616 |