Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates
Organocopper species are widely used in synthetic chemistry. Here the authors study the structure of the anionic complex formed from copper salts and lithium halides, showing it to be a key intermediate in the formation of organocuprates, and also show that Cu(II) precursors can form Gilman reagents...
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Nature Portfolio
2017
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oai:doaj.org-article:7982f2d466c64e33a36e679b8857883e2021-12-02T14:40:48ZUnravelling the hidden link of lithium halides and application in the synthesis of organocuprates10.1038/ncomms147942041-1723https://doaj.org/article/7982f2d466c64e33a36e679b8857883e2017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14794https://doaj.org/toc/2041-1723Organocopper species are widely used in synthetic chemistry. Here the authors study the structure of the anionic complex formed from copper salts and lithium halides, showing it to be a key intermediate in the formation of organocuprates, and also show that Cu(II) precursors can form Gilman reagents.Hong YiDali YangJie XinXiaotian QiYu LanYi DengChih-Wen PaoJyh-Fu LeeAiwen LeiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-6 (2017) |
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Science Q Hong Yi Dali Yang Jie Xin Xiaotian Qi Yu Lan Yi Deng Chih-Wen Pao Jyh-Fu Lee Aiwen Lei Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates |
description |
Organocopper species are widely used in synthetic chemistry. Here the authors study the structure of the anionic complex formed from copper salts and lithium halides, showing it to be a key intermediate in the formation of organocuprates, and also show that Cu(II) precursors can form Gilman reagents. |
format |
article |
author |
Hong Yi Dali Yang Jie Xin Xiaotian Qi Yu Lan Yi Deng Chih-Wen Pao Jyh-Fu Lee Aiwen Lei |
author_facet |
Hong Yi Dali Yang Jie Xin Xiaotian Qi Yu Lan Yi Deng Chih-Wen Pao Jyh-Fu Lee Aiwen Lei |
author_sort |
Hong Yi |
title |
Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates |
title_short |
Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates |
title_full |
Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates |
title_fullStr |
Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates |
title_full_unstemmed |
Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates |
title_sort |
unravelling the hidden link of lithium halides and application in the synthesis of organocuprates |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/7982f2d466c64e33a36e679b8857883e |
work_keys_str_mv |
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_version_ |
1718390119819378688 |