Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates

Organocopper species are widely used in synthetic chemistry. Here the authors study the structure of the anionic complex formed from copper salts and lithium halides, showing it to be a key intermediate in the formation of organocuprates, and also show that Cu(II) precursors can form Gilman reagents...

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Autores principales: Hong Yi, Dali Yang, Jie Xin, Xiaotian Qi, Yu Lan, Yi Deng, Chih-Wen Pao, Jyh-Fu Lee, Aiwen Lei
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/7982f2d466c64e33a36e679b8857883e
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spelling oai:doaj.org-article:7982f2d466c64e33a36e679b8857883e2021-12-02T14:40:48ZUnravelling the hidden link of lithium halides and application in the synthesis of organocuprates10.1038/ncomms147942041-1723https://doaj.org/article/7982f2d466c64e33a36e679b8857883e2017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14794https://doaj.org/toc/2041-1723Organocopper species are widely used in synthetic chemistry. Here the authors study the structure of the anionic complex formed from copper salts and lithium halides, showing it to be a key intermediate in the formation of organocuprates, and also show that Cu(II) precursors can form Gilman reagents.Hong YiDali YangJie XinXiaotian QiYu LanYi DengChih-Wen PaoJyh-Fu LeeAiwen LeiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-6 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Hong Yi
Dali Yang
Jie Xin
Xiaotian Qi
Yu Lan
Yi Deng
Chih-Wen Pao
Jyh-Fu Lee
Aiwen Lei
Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates
description Organocopper species are widely used in synthetic chemistry. Here the authors study the structure of the anionic complex formed from copper salts and lithium halides, showing it to be a key intermediate in the formation of organocuprates, and also show that Cu(II) precursors can form Gilman reagents.
format article
author Hong Yi
Dali Yang
Jie Xin
Xiaotian Qi
Yu Lan
Yi Deng
Chih-Wen Pao
Jyh-Fu Lee
Aiwen Lei
author_facet Hong Yi
Dali Yang
Jie Xin
Xiaotian Qi
Yu Lan
Yi Deng
Chih-Wen Pao
Jyh-Fu Lee
Aiwen Lei
author_sort Hong Yi
title Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates
title_short Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates
title_full Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates
title_fullStr Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates
title_full_unstemmed Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates
title_sort unravelling the hidden link of lithium halides and application in the synthesis of organocuprates
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/7982f2d466c64e33a36e679b8857883e
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