Copper-catalyzed C(sp)-C(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature

The first and environmentally benign oxidative cross coupling of stable trimethylsilylalkynoate with different arylboronic acids was developed. This reaction proceeded efficiently in the presence of Cu(OAc)2 at room temperature through the activation of Si–C bond by catalytic Cs2CO3, providing vari...

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Autores principales:	Jinghong Min, Zhanjiang Zheng, Shuaishuai Huang, Rongrong He, Zheng Xu, Jean Philippe Bouillon, Liwen Xu
Formato:	article
Lenguaje:	EN
Publicado:	KeAi Communications Co. Ltd. 2021
Materias:	Oxidative cross coupling Copper catalysis Si–C bond Cleavage Pentacoordinate silane Cs2CO3 activation Chemical technology TP1-1185 Biochemistry QD415-436
Acceso en línea:	https://doaj.org/article/7991734b2fa34cc2ba1b418a4ec07b17
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spelling	oai:doaj.org-article:7991734b2fa34cc2ba1b418a4ec07b172021-12-02T05:03:58ZCopper-catalyzed C(sp)-C(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature2666-554910.1016/j.gresc.2021.09.003https://doaj.org/article/7991734b2fa34cc2ba1b418a4ec07b172021-11-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2666554921000818https://doaj.org/toc/2666-5549The first and environmentally benign oxidative cross coupling of stable trimethylsilylalkynoate with different arylboronic acids was developed. This reaction proceeded efficiently in the presence of Cu(OAc)2 at room temperature through the activation of Si–C bond by catalytic Cs2CO3, providing various methyl arylpropiolates in good yields with a broad substrate scope under mild conditions.Jinghong MinZhanjiang ZhengShuaishuai HuangRongrong HeZheng XuJean Philippe BouillonLiwen XuKeAi Communications Co. Ltd.articleOxidative cross couplingCopper catalysisSi–C bond CleavagePentacoordinate silaneCs2CO3 activationChemical technologyTP1-1185BiochemistryQD415-436ENGreen Synthesis and Catalysis, Vol 2, Iss 4, Pp 350-355 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Oxidative cross coupling Copper catalysis Si–C bond Cleavage Pentacoordinate silane Cs2CO3 activation Chemical technology TP1-1185 Biochemistry QD415-436
spellingShingle	Oxidative cross coupling Copper catalysis Si–C bond Cleavage Pentacoordinate silane Cs2CO3 activation Chemical technology TP1-1185 Biochemistry QD415-436 Jinghong Min Zhanjiang Zheng Shuaishuai Huang Rongrong He Zheng Xu Jean Philippe Bouillon Liwen Xu Copper-catalyzed C(sp)-C(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature
description	The first and environmentally benign oxidative cross coupling of stable trimethylsilylalkynoate with different arylboronic acids was developed. This reaction proceeded efficiently in the presence of Cu(OAc)2 at room temperature through the activation of Si–C bond by catalytic Cs2CO3, providing various methyl arylpropiolates in good yields with a broad substrate scope under mild conditions.
format	article
author	Jinghong Min Zhanjiang Zheng Shuaishuai Huang Rongrong He Zheng Xu Jean Philippe Bouillon Liwen Xu
author_facet	Jinghong Min Zhanjiang Zheng Shuaishuai Huang Rongrong He Zheng Xu Jean Philippe Bouillon Liwen Xu
author_sort	Jinghong Min
title	Copper-catalyzed C(sp)-C(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature
title_short	Copper-catalyzed C(sp)-C(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature
title_full	Copper-catalyzed C(sp)-C(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature
title_fullStr	Copper-catalyzed C(sp)-C(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature
title_full_unstemmed	Copper-catalyzed C(sp)-C(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature
title_sort	copper-catalyzed c(sp)-c(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature
publisher	KeAi Communications Co. Ltd.
publishDate	2021
url	https://doaj.org/article/7991734b2fa34cc2ba1b418a4ec07b17
work_keys_str_mv	AT jinghongmin coppercatalyzedcspcsp2oxidativecrosscouplingreactiontoaccesstomethylarylpropiolatesatroomtemperature AT zhanjiangzheng coppercatalyzedcspcsp2oxidativecrosscouplingreactiontoaccesstomethylarylpropiolatesatroomtemperature AT shuaishuaihuang coppercatalyzedcspcsp2oxidativecrosscouplingreactiontoaccesstomethylarylpropiolatesatroomtemperature AT rongronghe coppercatalyzedcspcsp2oxidativecrosscouplingreactiontoaccesstomethylarylpropiolatesatroomtemperature AT zhengxu coppercatalyzedcspcsp2oxidativecrosscouplingreactiontoaccesstomethylarylpropiolatesatroomtemperature AT jeanphilippebouillon coppercatalyzedcspcsp2oxidativecrosscouplingreactiontoaccesstomethylarylpropiolatesatroomtemperature AT liwenxu coppercatalyzedcspcsp2oxidativecrosscouplingreactiontoaccesstomethylarylpropiolatesatroomtemperature
_version_	1718400659135397888

Copper-catalyzed C(sp)-C(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature

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