Surface single-molecule dynamics controlled by entropy at low temperatures
STM is capable of imaging the configurations of molecules on surfaces and measuring the rate of transitions between them. Here the authors demonstrate that, controlled by the STM tip position, the entropic and conservative forces on the molecule can modify the rate by orders of magnitude.
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Nature Portfolio
2017
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oai:doaj.org-article:7998a44cdfda418181faa9bd14a4595c2021-12-02T17:01:25ZSurface single-molecule dynamics controlled by entropy at low temperatures10.1038/ncomms144042041-1723https://doaj.org/article/7998a44cdfda418181faa9bd14a4595c2017-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms14404https://doaj.org/toc/2041-1723STM is capable of imaging the configurations of molecules on surfaces and measuring the rate of transitions between them. Here the authors demonstrate that, controlled by the STM tip position, the entropic and conservative forces on the molecule can modify the rate by orders of magnitude.J. C. GehrigM. PenedoM. ParschauJ. SchwenkM. A. MarioniE. W. HudsonH. J. HugNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017) |
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Science Q J. C. Gehrig M. Penedo M. Parschau J. Schwenk M. A. Marioni E. W. Hudson H. J. Hug Surface single-molecule dynamics controlled by entropy at low temperatures |
description |
STM is capable of imaging the configurations of molecules on surfaces and measuring the rate of transitions between them. Here the authors demonstrate that, controlled by the STM tip position, the entropic and conservative forces on the molecule can modify the rate by orders of magnitude. |
format |
article |
author |
J. C. Gehrig M. Penedo M. Parschau J. Schwenk M. A. Marioni E. W. Hudson H. J. Hug |
author_facet |
J. C. Gehrig M. Penedo M. Parschau J. Schwenk M. A. Marioni E. W. Hudson H. J. Hug |
author_sort |
J. C. Gehrig |
title |
Surface single-molecule dynamics controlled by entropy at low temperatures |
title_short |
Surface single-molecule dynamics controlled by entropy at low temperatures |
title_full |
Surface single-molecule dynamics controlled by entropy at low temperatures |
title_fullStr |
Surface single-molecule dynamics controlled by entropy at low temperatures |
title_full_unstemmed |
Surface single-molecule dynamics controlled by entropy at low temperatures |
title_sort |
surface single-molecule dynamics controlled by entropy at low temperatures |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/7998a44cdfda418181faa9bd14a4595c |
work_keys_str_mv |
AT jcgehrig surfacesinglemoleculedynamicscontrolledbyentropyatlowtemperatures AT mpenedo surfacesinglemoleculedynamicscontrolledbyentropyatlowtemperatures AT mparschau surfacesinglemoleculedynamicscontrolledbyentropyatlowtemperatures AT jschwenk surfacesinglemoleculedynamicscontrolledbyentropyatlowtemperatures AT mamarioni surfacesinglemoleculedynamicscontrolledbyentropyatlowtemperatures AT ewhudson surfacesinglemoleculedynamicscontrolledbyentropyatlowtemperatures AT hjhug surfacesinglemoleculedynamicscontrolledbyentropyatlowtemperatures |
_version_ |
1718382153060843520 |