An Improved Speciation Method Combining IC with ICPOES and Its Application to Iodide and Iodate Diffusion Behavior in Compacted Bentonite Clay
An accurate and effective method combining ion chromatography (IC) and inductively coupled plasma optical emission spectrometry (ICP-OES) was applied in this work to qualitatively and quantitatively analyze individual and co-existing iodide (I<sup>−</sup>) and iodate (IO<sub>3</...
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2021
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oai:doaj.org-article:7b230859e5f94eb29f1999193e7bfb6f2021-11-25T18:16:00ZAn Improved Speciation Method Combining IC with ICPOES and Its Application to Iodide and Iodate Diffusion Behavior in Compacted Bentonite Clay10.3390/ma142270561996-1944https://doaj.org/article/7b230859e5f94eb29f1999193e7bfb6f2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/22/7056https://doaj.org/toc/1996-1944An accurate and effective method combining ion chromatography (IC) and inductively coupled plasma optical emission spectrometry (ICP-OES) was applied in this work to qualitatively and quantitatively analyze individual and co-existing iodide (I<sup>−</sup>) and iodate (IO<sub>3</sub><sup>−</sup>) at various concentrations. More specifically, a very strong linear relationship for the peak area for the co-existing I<sup>−</sup> and IO<sub>3</sub><sup>−</sup> ions was reached, and a high resolution value between two peaks was observed, which proves the effectiveness of our combined IC-ICP-OES method at analyzing iodine species. We observed lower accessible porosity for the diffusion of both I<sup>−</sup> and IO<sub>3</sub><sup>−</sup> in samples of bentonite clay using IC-ICP-OES detection methods, where the effective diffusion coefficient varied based on the anion exclusion effect and the size of the diffusing molecules. In fact, the distribution coefficients (<i>K<sub>d</sub></i>) of both I<sup>−</sup> and IO<sub>3</sub><sup>−</sup> were close to 0, which indicates that there was no adsorption on bentonite clay. This finding can be explained by the fact that no change in speciation took place during the diffusion of I<sup>−</sup> and IO<sub>3</sub><sup>−</sup> ions in bentonite clay. Our IC-ICP-OES method can be used to estimate the diffusion coefficients of various iodine species in natural environments.Chuan-Pin LeeYanqin HuDongyang ChenEnhui WuZiteng WangZijin WenNeng-Chuan TienFan YangShih-Chin TsaiYunfeng ShiYi-Ling LiuMDPI AGarticleiodide (I<sup>−</sup>)iodate (IO<sub>3</sub><sup>−</sup>)IC-ICPOESbentoniteeffective diffusion coefficientaccessible porosityTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 7056, p 7056 (2021) |
| institution |
DOAJ |
| collection |
DOAJ |
| language |
EN |
| topic |
iodide (I<sup>−</sup>) iodate (IO<sub>3</sub><sup>−</sup>) IC-ICPOES bentonite effective diffusion coefficient accessible porosity Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 |
| spellingShingle |
iodide (I<sup>−</sup>) iodate (IO<sub>3</sub><sup>−</sup>) IC-ICPOES bentonite effective diffusion coefficient accessible porosity Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 Chuan-Pin Lee Yanqin Hu Dongyang Chen Enhui Wu Ziteng Wang Zijin Wen Neng-Chuan Tien Fan Yang Shih-Chin Tsai Yunfeng Shi Yi-Ling Liu An Improved Speciation Method Combining IC with ICPOES and Its Application to Iodide and Iodate Diffusion Behavior in Compacted Bentonite Clay |
| description |
An accurate and effective method combining ion chromatography (IC) and inductively coupled plasma optical emission spectrometry (ICP-OES) was applied in this work to qualitatively and quantitatively analyze individual and co-existing iodide (I<sup>−</sup>) and iodate (IO<sub>3</sub><sup>−</sup>) at various concentrations. More specifically, a very strong linear relationship for the peak area for the co-existing I<sup>−</sup> and IO<sub>3</sub><sup>−</sup> ions was reached, and a high resolution value between two peaks was observed, which proves the effectiveness of our combined IC-ICP-OES method at analyzing iodine species. We observed lower accessible porosity for the diffusion of both I<sup>−</sup> and IO<sub>3</sub><sup>−</sup> in samples of bentonite clay using IC-ICP-OES detection methods, where the effective diffusion coefficient varied based on the anion exclusion effect and the size of the diffusing molecules. In fact, the distribution coefficients (<i>K<sub>d</sub></i>) of both I<sup>−</sup> and IO<sub>3</sub><sup>−</sup> were close to 0, which indicates that there was no adsorption on bentonite clay. This finding can be explained by the fact that no change in speciation took place during the diffusion of I<sup>−</sup> and IO<sub>3</sub><sup>−</sup> ions in bentonite clay. Our IC-ICP-OES method can be used to estimate the diffusion coefficients of various iodine species in natural environments. |
| format |
article |
| author |
Chuan-Pin Lee Yanqin Hu Dongyang Chen Enhui Wu Ziteng Wang Zijin Wen Neng-Chuan Tien Fan Yang Shih-Chin Tsai Yunfeng Shi Yi-Ling Liu |
| author_facet |
Chuan-Pin Lee Yanqin Hu Dongyang Chen Enhui Wu Ziteng Wang Zijin Wen Neng-Chuan Tien Fan Yang Shih-Chin Tsai Yunfeng Shi Yi-Ling Liu |
| author_sort |
Chuan-Pin Lee |
| title |
An Improved Speciation Method Combining IC with ICPOES and Its Application to Iodide and Iodate Diffusion Behavior in Compacted Bentonite Clay |
| title_short |
An Improved Speciation Method Combining IC with ICPOES and Its Application to Iodide and Iodate Diffusion Behavior in Compacted Bentonite Clay |
| title_full |
An Improved Speciation Method Combining IC with ICPOES and Its Application to Iodide and Iodate Diffusion Behavior in Compacted Bentonite Clay |
| title_fullStr |
An Improved Speciation Method Combining IC with ICPOES and Its Application to Iodide and Iodate Diffusion Behavior in Compacted Bentonite Clay |
| title_full_unstemmed |
An Improved Speciation Method Combining IC with ICPOES and Its Application to Iodide and Iodate Diffusion Behavior in Compacted Bentonite Clay |
| title_sort |
improved speciation method combining ic with icpoes and its application to iodide and iodate diffusion behavior in compacted bentonite clay |
| publisher |
MDPI AG |
| publishDate |
2021 |
| url |
https://doaj.org/article/7b230859e5f94eb29f1999193e7bfb6f |
| work_keys_str_mv |
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