Copper(I)-catalysed site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T

Organochlorides are widespread in natural products, therefore the methods for site-selective chlorination at specific C–H bonds are of great interest. Here, the authors report a copper(I)-catalysed synthetic method for the efficient site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones a...

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Autores principales:	Jianwen Jin, Yichao Zhao, Sara Helen Kyne, Kaveh Farshadfar, Alireza Ariafard, Philip Wai Hong Chan
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/7bbab856bfbd47db849888e5a399c64e
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spelling	oai:doaj.org-article:7bbab856bfbd47db849888e5a399c64e2021-12-02T16:32:13ZCopper(I)-catalysed site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T10.1038/s41467-021-23988-y2041-1723https://doaj.org/article/7bbab856bfbd47db849888e5a399c64e2021-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23988-yhttps://doaj.org/toc/2041-1723Organochlorides are widespread in natural products, therefore the methods for site-selective chlorination at specific C–H bonds are of great interest. Here, the authors report a copper(I)-catalysed synthetic method for the efficient site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T at room temperature.Jianwen JinYichao ZhaoSara Helen KyneKaveh FarshadfarAlireza AriafardPhilip Wai Hong ChanNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-12 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jianwen Jin Yichao Zhao Sara Helen Kyne Kaveh Farshadfar Alireza Ariafard Philip Wai Hong Chan Copper(I)-catalysed site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T
description	Organochlorides are widespread in natural products, therefore the methods for site-selective chlorination at specific C–H bonds are of great interest. Here, the authors report a copper(I)-catalysed synthetic method for the efficient site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T at room temperature.
format	article
author	Jianwen Jin Yichao Zhao Sara Helen Kyne Kaveh Farshadfar Alireza Ariafard Philip Wai Hong Chan
author_facet	Jianwen Jin Yichao Zhao Sara Helen Kyne Kaveh Farshadfar Alireza Ariafard Philip Wai Hong Chan
author_sort	Jianwen Jin
title	Copper(I)-catalysed site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T
title_short	Copper(I)-catalysed site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T
title_full	Copper(I)-catalysed site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T
title_fullStr	Copper(I)-catalysed site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T
title_full_unstemmed	Copper(I)-catalysed site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T
title_sort	copper(i)-catalysed site-selective c(sp 3)–h bond chlorination of ketones, (e)-enones and alkylbenzenes by dichloramine-t
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/7bbab856bfbd47db849888e5a399c64e
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Copper(I)-catalysed site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T

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