Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles

Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization.

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Detalles Bibliográficos
Autores principales: Takashi Nakamura, Yuya Kaneko, Eiji Nishibori, Tatsuya Nabeshima
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/7bdf43e3bc044d72b0eff2bebb8719c1
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Sumario:Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization.