Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization.
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Nature Portfolio
2017
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oai:doaj.org-article:7bdf43e3bc044d72b0eff2bebb8719c12021-12-02T10:48:10ZMolecular recognition by multiple metal coordination inside wavy-stacked macrocycles10.1038/s41467-017-00076-82041-1723https://doaj.org/article/7bdf43e3bc044d72b0eff2bebb8719c12017-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00076-8https://doaj.org/toc/2041-1723Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization.Takashi NakamuraYuya KanekoEiji NishiboriTatsuya NabeshimaNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017) |
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Science Q Takashi Nakamura Yuya Kaneko Eiji Nishibori Tatsuya Nabeshima Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles |
description |
Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization. |
format |
article |
author |
Takashi Nakamura Yuya Kaneko Eiji Nishibori Tatsuya Nabeshima |
author_facet |
Takashi Nakamura Yuya Kaneko Eiji Nishibori Tatsuya Nabeshima |
author_sort |
Takashi Nakamura |
title |
Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles |
title_short |
Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles |
title_full |
Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles |
title_fullStr |
Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles |
title_full_unstemmed |
Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles |
title_sort |
molecular recognition by multiple metal coordination inside wavy-stacked macrocycles |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/7bdf43e3bc044d72b0eff2bebb8719c1 |
work_keys_str_mv |
AT takashinakamura molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles AT yuyakaneko molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles AT eijinishibori molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles AT tatsuyanabeshima molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles |
_version_ |
1718396657518772224 |