Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles

Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization.

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Autores principales: Takashi Nakamura, Yuya Kaneko, Eiji Nishibori, Tatsuya Nabeshima
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/7bdf43e3bc044d72b0eff2bebb8719c1
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spelling oai:doaj.org-article:7bdf43e3bc044d72b0eff2bebb8719c12021-12-02T10:48:10ZMolecular recognition by multiple metal coordination inside wavy-stacked macrocycles10.1038/s41467-017-00076-82041-1723https://doaj.org/article/7bdf43e3bc044d72b0eff2bebb8719c12017-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00076-8https://doaj.org/toc/2041-1723Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization.Takashi NakamuraYuya KanekoEiji NishiboriTatsuya NabeshimaNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Takashi Nakamura
Yuya Kaneko
Eiji Nishibori
Tatsuya Nabeshima
Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
description Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization.
format article
author Takashi Nakamura
Yuya Kaneko
Eiji Nishibori
Tatsuya Nabeshima
author_facet Takashi Nakamura
Yuya Kaneko
Eiji Nishibori
Tatsuya Nabeshima
author_sort Takashi Nakamura
title Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
title_short Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
title_full Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
title_fullStr Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
title_full_unstemmed Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
title_sort molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/7bdf43e3bc044d72b0eff2bebb8719c1
work_keys_str_mv AT takashinakamura molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles
AT yuyakaneko molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles
AT eijinishibori molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles
AT tatsuyanabeshima molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles
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