Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles

Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization.

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Bibliographic Details
Main Authors:	Takashi Nakamura, Yuya Kaneko, Eiji Nishibori, Tatsuya Nabeshima
Format:	article
Language:	EN
Published:	Nature Portfolio 2017
Subjects:	Science Q
Online Access:	https://doaj.org/article/7bdf43e3bc044d72b0eff2bebb8719c1
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id	oai:doaj.org-article:7bdf43e3bc044d72b0eff2bebb8719c1
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spelling	oai:doaj.org-article:7bdf43e3bc044d72b0eff2bebb8719c12021-12-02T10:48:10ZMolecular recognition by multiple metal coordination inside wavy-stacked macrocycles10.1038/s41467-017-00076-82041-1723https://doaj.org/article/7bdf43e3bc044d72b0eff2bebb8719c12017-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00076-8https://doaj.org/toc/2041-1723Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization.Takashi NakamuraYuya KanekoEiji NishiboriTatsuya NabeshimaNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Takashi Nakamura Yuya Kaneko Eiji Nishibori Tatsuya Nabeshima Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
description	Synergistic use of coordination bonds that are strong and reversible realizes unique molecular recognition in artificial systems. Here, the authors show that a zinc-based metallomacrocyle can bind dicarboxylic acids of suitable length at specific metal sites by shape deformation and dimerization.
format	article
author	Takashi Nakamura Yuya Kaneko Eiji Nishibori Tatsuya Nabeshima
author_facet	Takashi Nakamura Yuya Kaneko Eiji Nishibori Tatsuya Nabeshima
author_sort	Takashi Nakamura
title	Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
title_short	Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
title_full	Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
title_fullStr	Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
title_full_unstemmed	Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
title_sort	molecular recognition by multiple metal coordination inside wavy-stacked macrocycles
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/7bdf43e3bc044d72b0eff2bebb8719c1
work_keys_str_mv	AT takashinakamura molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles AT yuyakaneko molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles AT eijinishibori molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles AT tatsuyanabeshima molecularrecognitionbymultiplemetalcoordinationinsidewavystackedmacrocycles
_version_	1718396657518772224

Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles

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