Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts

The question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition.

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Autores principales: Yizhi Xiang, Libor Kovarik, Norbert Kruse
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/7bf032a5a699408cb0d8de527d3dc0c6
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spelling oai:doaj.org-article:7bf032a5a699408cb0d8de527d3dc0c62021-12-02T15:35:59ZRate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts10.1038/s41467-019-11836-z2041-1723https://doaj.org/article/7bf032a5a699408cb0d8de527d3dc0c62019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11836-zhttps://doaj.org/toc/2041-1723The question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition.Yizhi XiangLibor KovarikNorbert KruseNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yizhi Xiang
Libor Kovarik
Norbert Kruse
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts
description The question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition.
format article
author Yizhi Xiang
Libor Kovarik
Norbert Kruse
author_facet Yizhi Xiang
Libor Kovarik
Norbert Kruse
author_sort Yizhi Xiang
title Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts
title_short Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts
title_full Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts
title_fullStr Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts
title_full_unstemmed Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts
title_sort rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted co/mnox catalysts
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/7bf032a5a699408cb0d8de527d3dc0c6
work_keys_str_mv AT yizhixiang rateandselectivityhysteresisduringthecarbonmonoxidehydrogenationoverpromotedcomnoxcatalysts
AT liborkovarik rateandselectivityhysteresisduringthecarbonmonoxidehydrogenationoverpromotedcomnoxcatalysts
AT norbertkruse rateandselectivityhysteresisduringthecarbonmonoxidehydrogenationoverpromotedcomnoxcatalysts
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