Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts
The question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition.
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Nature Portfolio
2019
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oai:doaj.org-article:7bf032a5a699408cb0d8de527d3dc0c62021-12-02T15:35:59ZRate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts10.1038/s41467-019-11836-z2041-1723https://doaj.org/article/7bf032a5a699408cb0d8de527d3dc0c62019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11836-zhttps://doaj.org/toc/2041-1723The question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition.Yizhi XiangLibor KovarikNorbert KruseNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019) |
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Science Q Yizhi Xiang Libor Kovarik Norbert Kruse Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
description |
The question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition. |
format |
article |
author |
Yizhi Xiang Libor Kovarik Norbert Kruse |
author_facet |
Yizhi Xiang Libor Kovarik Norbert Kruse |
author_sort |
Yizhi Xiang |
title |
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
title_short |
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
title_full |
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
title_fullStr |
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
title_full_unstemmed |
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
title_sort |
rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted co/mnox catalysts |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/7bf032a5a699408cb0d8de527d3dc0c6 |
work_keys_str_mv |
AT yizhixiang rateandselectivityhysteresisduringthecarbonmonoxidehydrogenationoverpromotedcomnoxcatalysts AT liborkovarik rateandselectivityhysteresisduringthecarbonmonoxidehydrogenationoverpromotedcomnoxcatalysts AT norbertkruse rateandselectivityhysteresisduringthecarbonmonoxidehydrogenationoverpromotedcomnoxcatalysts |
_version_ |
1718386362161299456 |