Iridates from the molecular side

Iridates from the molecular side

Iridates are known to exhibit a range of exotic electronic and magnetic behaviours but it is difficult to prepare isolated [IrO6]8− species via soft chemical routes. Here, the authors isolate the isoelectronic [IrF6]2−complex, and assess it as a model and for iridate analogues.

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Detalles Bibliográficos
Autores principales: Kasper S. Pedersen, Jesper Bendix, Alain Tressaud, Etienne Durand, Høgni Weihe, Zaher Salman, Thorbjørn J Morsing, Daniel N. Woodruff, Yanhua Lan, Wolfgang Wernsdorfer, Corine Mathonière, Stergios Piligkos, Sophia I. Klokishner, Serghei Ostrovsky, Katharina Ollefs, Fabrice Wilhelm, Andrei Rogalev, Rodolphe Clérac
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
Materias:
Science
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Acceso en línea:https://doaj.org/article/7c58a1eb9cd241d7abb9b1557d05237c
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Descripción
Sumario:Iridates are known to exhibit a range of exotic electronic and magnetic behaviours but it is difficult to prepare isolated [IrO6]8− species via soft chemical routes. Here, the authors isolate the isoelectronic [IrF6]2−complex, and assess it as a model and for iridate analogues.

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