Controllable Synthesis of 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) Benzene-Based MOFs

The growing interest in metal–organic frameworks (MOFs) in both industrial and scientific circles has increased in the last twenty years, owing to their crystallinity, structural versatility, and controlled porosity. In this study, we present three novel MOFs obtained from the 1, 3, 5-tris (1H-benzo...

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Autores principales:	Sanjit Gaikwad, Ravi Kumar Cheedarala, Ranjit Gaikwad, Soonho Kim, Sangil Han
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	MOF adsorption CO<sub>2</sub> capture porous material solvothermal synthesis Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/7cc44dad31f94b3db338b529cf587c30
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spelling	oai:doaj.org-article:7cc44dad31f94b3db338b529cf587c302021-11-11T14:59:12ZControllable Synthesis of 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) Benzene-Based MOFs10.3390/app112198562076-3417https://doaj.org/article/7cc44dad31f94b3db338b529cf587c302021-10-01T00:00:00Zhttps://www.mdpi.com/2076-3417/11/21/9856https://doaj.org/toc/2076-3417The growing interest in metal–organic frameworks (MOFs) in both industrial and scientific circles has increased in the last twenty years, owing to their crystallinity, structural versatility, and controlled porosity. In this study, we present three novel MOFs obtained from the 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) benzene (TIBM) organic linker. The formed TIBM crystal powders were characterized by scanning electron microscopy (SEM) to estimate the morphology of the particles, powder X-ray diffraction (XRD) to confirm the crystal structure, Brunauer–Emmett–Teller (BET) method for structural analysis, and thermogravimetric measurements to examine the thermal stability. The TIBM-Cu MOF showed excellent CO<sub>2</sub> (3.60 mmol/g) adsorption capacity at 1 bar and 298 K, because of the open Cu site, compared to TIBM-Cr (1.6 mmol/g) and TIBM-Al (2.1 mmol/g). Additionally, due to the high porosity (0.3–1.5 nm), TIBM-Cu MOF showed a considerable CO<sub>2</sub>/N<sub>2</sub> selectivity (53) compared to TIBM-Al (35) and TIBM-Cr (10).Sanjit GaikwadRavi Kumar CheedaralaRanjit GaikwadSoonho KimSangil HanMDPI AGarticleMOFadsorptionCO<sub>2</sub> captureporous materialsolvothermal synthesisTechnologyTEngineering (General). Civil engineering (General)TA1-2040Biology (General)QH301-705.5PhysicsQC1-999ChemistryQD1-999ENApplied Sciences, Vol 11, Iss 9856, p 9856 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	MOF adsorption CO<sub>2</sub> capture porous material solvothermal synthesis Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999
spellingShingle	MOF adsorption CO<sub>2</sub> capture porous material solvothermal synthesis Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999 Sanjit Gaikwad Ravi Kumar Cheedarala Ranjit Gaikwad Soonho Kim Sangil Han Controllable Synthesis of 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) Benzene-Based MOFs
description	The growing interest in metal–organic frameworks (MOFs) in both industrial and scientific circles has increased in the last twenty years, owing to their crystallinity, structural versatility, and controlled porosity. In this study, we present three novel MOFs obtained from the 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) benzene (TIBM) organic linker. The formed TIBM crystal powders were characterized by scanning electron microscopy (SEM) to estimate the morphology of the particles, powder X-ray diffraction (XRD) to confirm the crystal structure, Brunauer–Emmett–Teller (BET) method for structural analysis, and thermogravimetric measurements to examine the thermal stability. The TIBM-Cu MOF showed excellent CO<sub>2</sub> (3.60 mmol/g) adsorption capacity at 1 bar and 298 K, because of the open Cu site, compared to TIBM-Cr (1.6 mmol/g) and TIBM-Al (2.1 mmol/g). Additionally, due to the high porosity (0.3–1.5 nm), TIBM-Cu MOF showed a considerable CO<sub>2</sub>/N<sub>2</sub> selectivity (53) compared to TIBM-Al (35) and TIBM-Cr (10).
format	article
author	Sanjit Gaikwad Ravi Kumar Cheedarala Ranjit Gaikwad Soonho Kim Sangil Han
author_facet	Sanjit Gaikwad Ravi Kumar Cheedarala Ranjit Gaikwad Soonho Kim Sangil Han
author_sort	Sanjit Gaikwad
title	Controllable Synthesis of 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) Benzene-Based MOFs
title_short	Controllable Synthesis of 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) Benzene-Based MOFs
title_full	Controllable Synthesis of 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) Benzene-Based MOFs
title_fullStr	Controllable Synthesis of 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) Benzene-Based MOFs
title_full_unstemmed	Controllable Synthesis of 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) Benzene-Based MOFs
title_sort	controllable synthesis of 1, 3, 5-tris (1h-benzo[d]imidazole-2-yl) benzene-based mofs
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/7cc44dad31f94b3db338b529cf587c30
work_keys_str_mv	AT sanjitgaikwad controllablesynthesisof135tris1hbenzodimidazole2ylbenzenebasedmofs AT ravikumarcheedarala controllablesynthesisof135tris1hbenzodimidazole2ylbenzenebasedmofs AT ranjitgaikwad controllablesynthesisof135tris1hbenzodimidazole2ylbenzenebasedmofs AT soonhokim controllablesynthesisof135tris1hbenzodimidazole2ylbenzenebasedmofs AT sangilhan controllablesynthesisof135tris1hbenzodimidazole2ylbenzenebasedmofs
_version_	1718437902278459392

Controllable Synthesis of 1, 3, 5-tris (1H-benzo[d]imidazole-2-yl) Benzene-Based MOFs

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