Zn-based eutectic mixture as anolyte for hybrid redox flow batteries

Abstract Developing greener batteries with new chemistries is a formidable challenge, and a major focus for years to come. Redox flow batteries are receiving increasing research interest for grid-scale electrochemical energy storage owing to their unique architecture. However, challenges still remai...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Yiyu Wang, Zhihui Niu, Qi Zheng, Changkun Zhang, Jing Ye, Gaole Dai, Yu Zhao, Xiaohong Zhang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/7d20e56822ab41b6a62cb28a7b3173ce
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:7d20e56822ab41b6a62cb28a7b3173ce
record_format	dspace
spelling	oai:doaj.org-article:7d20e56822ab41b6a62cb28a7b3173ce2021-12-02T11:41:25ZZn-based eutectic mixture as anolyte for hybrid redox flow batteries10.1038/s41598-018-24059-x2045-2322https://doaj.org/article/7d20e56822ab41b6a62cb28a7b3173ce2018-04-01T00:00:00Zhttps://doi.org/10.1038/s41598-018-24059-xhttps://doaj.org/toc/2045-2322Abstract Developing greener batteries with new chemistries is a formidable challenge, and a major focus for years to come. Redox flow batteries are receiving increasing research interest for grid-scale electrochemical energy storage owing to their unique architecture. However, challenges still remain by their low energy density as well as corrosive and/or toxic electrolytes. An anolyte based on aprotic Zn deep-eutectic-solvent, which uses low cost, abundant and environmentally benign materials, exhibits a utilizable concentration of Zn2+ ca. 1.7 M, resulting in a reversible volumetric capacity of ca. 90 A h·L−1. Combined with high efficiencies and relatively low redox potential of −1.12 V vs. Ag/AgCl, such an anolyte provides an alternative way to explore a family of anolytes using new chemistries for rechargeable Zn batteries that meet the criteria for grid-scale electrical energy storage.Yiyu WangZhihui NiuQi ZhengChangkun ZhangJing YeGaole DaiYu ZhaoXiaohong ZhangNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 8, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Yiyu Wang Zhihui Niu Qi Zheng Changkun Zhang Jing Ye Gaole Dai Yu Zhao Xiaohong Zhang Zn-based eutectic mixture as anolyte for hybrid redox flow batteries
description	Abstract Developing greener batteries with new chemistries is a formidable challenge, and a major focus for years to come. Redox flow batteries are receiving increasing research interest for grid-scale electrochemical energy storage owing to their unique architecture. However, challenges still remain by their low energy density as well as corrosive and/or toxic electrolytes. An anolyte based on aprotic Zn deep-eutectic-solvent, which uses low cost, abundant and environmentally benign materials, exhibits a utilizable concentration of Zn2+ ca. 1.7 M, resulting in a reversible volumetric capacity of ca. 90 A h·L−1. Combined with high efficiencies and relatively low redox potential of −1.12 V vs. Ag/AgCl, such an anolyte provides an alternative way to explore a family of anolytes using new chemistries for rechargeable Zn batteries that meet the criteria for grid-scale electrical energy storage.
format	article
author	Yiyu Wang Zhihui Niu Qi Zheng Changkun Zhang Jing Ye Gaole Dai Yu Zhao Xiaohong Zhang
author_facet	Yiyu Wang Zhihui Niu Qi Zheng Changkun Zhang Jing Ye Gaole Dai Yu Zhao Xiaohong Zhang
author_sort	Yiyu Wang
title	Zn-based eutectic mixture as anolyte for hybrid redox flow batteries
title_short	Zn-based eutectic mixture as anolyte for hybrid redox flow batteries
title_full	Zn-based eutectic mixture as anolyte for hybrid redox flow batteries
title_fullStr	Zn-based eutectic mixture as anolyte for hybrid redox flow batteries
title_full_unstemmed	Zn-based eutectic mixture as anolyte for hybrid redox flow batteries
title_sort	zn-based eutectic mixture as anolyte for hybrid redox flow batteries
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/7d20e56822ab41b6a62cb28a7b3173ce
work_keys_str_mv	AT yiyuwang znbasedeutecticmixtureasanolyteforhybridredoxflowbatteries AT zhihuiniu znbasedeutecticmixtureasanolyteforhybridredoxflowbatteries AT qizheng znbasedeutecticmixtureasanolyteforhybridredoxflowbatteries AT changkunzhang znbasedeutecticmixtureasanolyteforhybridredoxflowbatteries AT jingye znbasedeutecticmixtureasanolyteforhybridredoxflowbatteries AT gaoledai znbasedeutecticmixtureasanolyteforhybridredoxflowbatteries AT yuzhao znbasedeutecticmixtureasanolyteforhybridredoxflowbatteries AT xiaohongzhang znbasedeutecticmixtureasanolyteforhybridredoxflowbatteries
_version_	1718395406501543936

Zn-based eutectic mixture as anolyte for hybrid redox flow batteries

Ejemplares similares