Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes

Controlling selectivity in the hydrosilylation of allenes poses serious challenges in terms of product stereochemistry. Here the authors show that the title reaction proceeds with excellent (Z)-selectivity by use of a cobalt catalyst in the presence of phosphine-based ligands.

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Détails bibliographiques
Auteurs principaux:	Chao Wang, Wei Jie Teo, Shaozhong Ge
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2017
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/7d9acfa72b1f4b9d96b8664f966346ef
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spelling	oai:doaj.org-article:7d9acfa72b1f4b9d96b8664f966346ef2021-12-02T15:38:31ZAccess to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes10.1038/s41467-017-02382-72041-1723https://doaj.org/article/7d9acfa72b1f4b9d96b8664f966346ef2017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02382-7https://doaj.org/toc/2041-1723Controlling selectivity in the hydrosilylation of allenes poses serious challenges in terms of product stereochemistry. Here the authors show that the title reaction proceeds with excellent (Z)-selectivity by use of a cobalt catalyst in the presence of phosphine-based ligands.Chao WangWei Jie TeoShaozhong GeNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-9 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chao Wang Wei Jie Teo Shaozhong Ge Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes
description	Controlling selectivity in the hydrosilylation of allenes poses serious challenges in terms of product stereochemistry. Here the authors show that the title reaction proceeds with excellent (Z)-selectivity by use of a cobalt catalyst in the presence of phosphine-based ligands.
format	article
author	Chao Wang Wei Jie Teo Shaozhong Ge
author_facet	Chao Wang Wei Jie Teo Shaozhong Ge
author_sort	Chao Wang
title	Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes
title_short	Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes
title_full	Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes
title_fullStr	Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes
title_full_unstemmed	Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes
title_sort	access to stereodefined (z)-allylsilanes and (z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/7d9acfa72b1f4b9d96b8664f966346ef
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Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes

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