Enhanced hydrogenation activity and diastereomeric interactions of methyl pyruvate co-adsorbed with R-1-(1-naphthyl)ethylamine on Pd(111)

Achiral sites on a catalyst can result in formation of racemic product, though this can be avoided where the chiral sites lead to enhanced reaction rates. Here, the authors report that for the hydrogenation of methyl pyruvate the chiral modifier enhances the hydrogenation reactivity by favouring the...

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Autores principales:	Mausumi Mahapatra, Luke Burkholder, Michael Garvey, Yun Bai, Dilano K. Saldin, Wilfred T. Tysoe
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/7da54bb2f16b4bcd9cf628b11bf04e83
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spelling	oai:doaj.org-article:7da54bb2f16b4bcd9cf628b11bf04e832021-12-02T14:39:51ZEnhanced hydrogenation activity and diastereomeric interactions of methyl pyruvate co-adsorbed with R-1-(1-naphthyl)ethylamine on Pd(111)10.1038/ncomms123802041-1723https://doaj.org/article/7da54bb2f16b4bcd9cf628b11bf04e832016-08-01T00:00:00Zhttps://doi.org/10.1038/ncomms12380https://doaj.org/toc/2041-1723Achiral sites on a catalyst can result in formation of racemic product, though this can be avoided where the chiral sites lead to enhanced reaction rates. Here, the authors report that for the hydrogenation of methyl pyruvate the chiral modifier enhances the hydrogenation reactivity by favouring the more reactive enol tautomer.Mausumi MahapatraLuke BurkholderMichael GarveyYun BaiDilano K. SaldinWilfred T. TysoeNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Mausumi Mahapatra Luke Burkholder Michael Garvey Yun Bai Dilano K. Saldin Wilfred T. Tysoe Enhanced hydrogenation activity and diastereomeric interactions of methyl pyruvate co-adsorbed with R-1-(1-naphthyl)ethylamine on Pd(111)
description	Achiral sites on a catalyst can result in formation of racemic product, though this can be avoided where the chiral sites lead to enhanced reaction rates. Here, the authors report that for the hydrogenation of methyl pyruvate the chiral modifier enhances the hydrogenation reactivity by favouring the more reactive enol tautomer.
format	article
author	Mausumi Mahapatra Luke Burkholder Michael Garvey Yun Bai Dilano K. Saldin Wilfred T. Tysoe
author_facet	Mausumi Mahapatra Luke Burkholder Michael Garvey Yun Bai Dilano K. Saldin Wilfred T. Tysoe
author_sort	Mausumi Mahapatra
title	Enhanced hydrogenation activity and diastereomeric interactions of methyl pyruvate co-adsorbed with R-1-(1-naphthyl)ethylamine on Pd(111)
title_short	Enhanced hydrogenation activity and diastereomeric interactions of methyl pyruvate co-adsorbed with R-1-(1-naphthyl)ethylamine on Pd(111)
title_full	Enhanced hydrogenation activity and diastereomeric interactions of methyl pyruvate co-adsorbed with R-1-(1-naphthyl)ethylamine on Pd(111)
title_fullStr	Enhanced hydrogenation activity and diastereomeric interactions of methyl pyruvate co-adsorbed with R-1-(1-naphthyl)ethylamine on Pd(111)
title_full_unstemmed	Enhanced hydrogenation activity and diastereomeric interactions of methyl pyruvate co-adsorbed with R-1-(1-naphthyl)ethylamine on Pd(111)
title_sort	enhanced hydrogenation activity and diastereomeric interactions of methyl pyruvate co-adsorbed with r-1-(1-naphthyl)ethylamine on pd(111)
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/7da54bb2f16b4bcd9cf628b11bf04e83
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Enhanced hydrogenation activity and diastereomeric interactions of methyl pyruvate co-adsorbed with R-1-(1-naphthyl)ethylamine on Pd(111)

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