Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties
Noble metal nanoclusters are commonly protected by thiolate, phosphine, or alkynyl ligands. Here, the authors synthesize two homoleptic amido-protected silver clusters, whose structures interconvert easily with changes of solvent due to the coordination flexibility and diverse binding modes of the n...
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| Autores principales: | , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2019
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/7db97729b27e4a96892ad95db7608756 |
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| Sumario: | Noble metal nanoclusters are commonly protected by thiolate, phosphine, or alkynyl ligands. Here, the authors synthesize two homoleptic amido-protected silver clusters, whose structures interconvert easily with changes of solvent due to the coordination flexibility and diverse binding modes of the nitrogen-donor ligands. |
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