Light-controlled switching of the spin state of iron(III)

Controlled switching of the spin state of transition metal ions is key in many enzymatic reactions, but difficult to replicate in synthetic systems. Here the authors report on an iron(III) porphyrin with a photochromic axial ligand that, in solution, reversibly switches between low-spin and high-spi...

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Autores principales:	Sreejith Shankar, Morten Peters, Kim Steinborn, Bahne Krahwinkel, Frank D. Sönnichsen, Dirk Grote, Wolfram Sander, Thomas Lohmiller, Olaf Rüdiger, Rainer Herges
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/7e0f36bc9b464a86be6b69a789e1005d
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spelling	oai:doaj.org-article:7e0f36bc9b464a86be6b69a789e1005d2021-12-02T17:31:13ZLight-controlled switching of the spin state of iron(III)10.1038/s41467-018-07023-12041-1723https://doaj.org/article/7e0f36bc9b464a86be6b69a789e1005d2018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07023-1https://doaj.org/toc/2041-1723Controlled switching of the spin state of transition metal ions is key in many enzymatic reactions, but difficult to replicate in synthetic systems. Here the authors report on an iron(III) porphyrin with a photochromic axial ligand that, in solution, reversibly switches between low-spin and high-spin upon irradiation with two different wavelengths.Sreejith ShankarMorten PetersKim SteinbornBahne KrahwinkelFrank D. SönnichsenDirk GroteWolfram SanderThomas LohmillerOlaf RüdigerRainer HergesNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-12 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Sreejith Shankar Morten Peters Kim Steinborn Bahne Krahwinkel Frank D. Sönnichsen Dirk Grote Wolfram Sander Thomas Lohmiller Olaf Rüdiger Rainer Herges Light-controlled switching of the spin state of iron(III)
description	Controlled switching of the spin state of transition metal ions is key in many enzymatic reactions, but difficult to replicate in synthetic systems. Here the authors report on an iron(III) porphyrin with a photochromic axial ligand that, in solution, reversibly switches between low-spin and high-spin upon irradiation with two different wavelengths.
format	article
author	Sreejith Shankar Morten Peters Kim Steinborn Bahne Krahwinkel Frank D. Sönnichsen Dirk Grote Wolfram Sander Thomas Lohmiller Olaf Rüdiger Rainer Herges
author_facet	Sreejith Shankar Morten Peters Kim Steinborn Bahne Krahwinkel Frank D. Sönnichsen Dirk Grote Wolfram Sander Thomas Lohmiller Olaf Rüdiger Rainer Herges
author_sort	Sreejith Shankar
title	Light-controlled switching of the spin state of iron(III)
title_short	Light-controlled switching of the spin state of iron(III)
title_full	Light-controlled switching of the spin state of iron(III)
title_fullStr	Light-controlled switching of the spin state of iron(III)
title_full_unstemmed	Light-controlled switching of the spin state of iron(III)
title_sort	light-controlled switching of the spin state of iron(iii)
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/7e0f36bc9b464a86be6b69a789e1005d
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Light-controlled switching of the spin state of iron(III)

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