Composition rules of Ni-base single crystal superalloys and its influence on creep properties via a cluster formula approach

Abstract The present work investigated the composition evolution of the TMS series of Ni-base single crystal (SC) superalloys in light of the cluster formula approach systematically. The cluster formula of SC superalloys could be expressed with $${[}\overline{{{\text{Al}}}} {-} \overline{{{\text{Ni}...

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Autores principales:	Chen Chen, Qing Wang, Chuang Dong, Yu Zhang, Honggang Dong
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/7e4c9c2a50f44d55b9f7271c79f003b2
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spelling	oai:doaj.org-article:7e4c9c2a50f44d55b9f7271c79f003b22021-12-02T11:43:58ZComposition rules of Ni-base single crystal superalloys and its influence on creep properties via a cluster formula approach10.1038/s41598-020-78690-82045-2322https://doaj.org/article/7e4c9c2a50f44d55b9f7271c79f003b22020-12-01T00:00:00Zhttps://doi.org/10.1038/s41598-020-78690-8https://doaj.org/toc/2045-2322Abstract The present work investigated the composition evolution of the TMS series of Ni-base single crystal (SC) superalloys in light of the cluster formula approach systematically. The cluster formula of SC superalloys could be expressed with $${[}\overline{{{\text{Al}}}} {-} \overline{{{\text{Ni}}}} 12{](}\overline{{{\text{Al}}}} {, }\overline{{{\text{Cr}}}} {)}m$$ [ Al ¯ - Ni ¯ 12 ] ( Al ¯ , Cr ¯ ) m , in which all the alloying elements were classified into three groups, Al series ( $$\overline{{{\text{Al}}}}$$ Al ¯ ), Cr series ( $$\overline{{{\text{Cr}}}}$$ Cr ¯ ), and Ni series ( $$\overline{{{\text{Ni}}}}$$ Ni ¯ ). It was found that the total atom number (Z) of the cluster formula units for TMS series of superalloys varies from Z ~ 17 to Z ~ 15.5, and then to Z ~ 16 with the alloy development from the 1st to the 6th generation, in which the superalloys with prominent creep resistance possess an ideal cluster formula of $${[}\overline{{{\text{Al}}}} {-} \overline{{{\text{Ni}}}} 12{](}\overline{{{\text{Al}}}} 1.5\overline{{{\text{Cr}}}} 1.5{)}$$ [ Al ¯ - Ni ¯ 12 ] ( Al ¯ 1.5 Cr ¯ 1.5 ) with Z = 16. Similar tendency of composition evolution also appears in the PWA and CMSX series of SC superalloys. Typical TMS series of superalloys with prominent creep properties generally exhibit a moderate lattice misfit of γ/γ′ which could render alloys with appropriate particle size of cuboidal γ′ precipitates to acquire a maximum strength increment by precipitation strengthening mechanism. More importantly, the relationship between the lattice misfit (δ) of γ/γ′ and the creep rupture lifetime (t r ) of superalloys was then established, showing a linear correlation in the form of lgt r –lg\|δ\|3/2 at both conditions of 900 °C/392 MPa and 1100 °C/137 MPa. Combined with the lattice misfit, the cluster formula approach would provide a new way to modify or optimize the compositions of Ni-base superalloys for further improvement of creep property.Chen ChenQing WangChuang DongYu ZhangHonggang DongNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 10, Iss 1, Pp 1-13 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Chen Chen Qing Wang Chuang Dong Yu Zhang Honggang Dong Composition rules of Ni-base single crystal superalloys and its influence on creep properties via a cluster formula approach
description	Abstract The present work investigated the composition evolution of the TMS series of Ni-base single crystal (SC) superalloys in light of the cluster formula approach systematically. The cluster formula of SC superalloys could be expressed with $${[}\overline{{{\text{Al}}}} {-} \overline{{{\text{Ni}}}} 12{](}\overline{{{\text{Al}}}} {, }\overline{{{\text{Cr}}}} {)}m$$ [ Al ¯ - Ni ¯ 12 ] ( Al ¯ , Cr ¯ ) m , in which all the alloying elements were classified into three groups, Al series ( $$\overline{{{\text{Al}}}}$$ Al ¯ ), Cr series ( $$\overline{{{\text{Cr}}}}$$ Cr ¯ ), and Ni series ( $$\overline{{{\text{Ni}}}}$$ Ni ¯ ). It was found that the total atom number (Z) of the cluster formula units for TMS series of superalloys varies from Z ~ 17 to Z ~ 15.5, and then to Z ~ 16 with the alloy development from the 1st to the 6th generation, in which the superalloys with prominent creep resistance possess an ideal cluster formula of $${[}\overline{{{\text{Al}}}} {-} \overline{{{\text{Ni}}}} 12{](}\overline{{{\text{Al}}}} 1.5\overline{{{\text{Cr}}}} 1.5{)}$$ [ Al ¯ - Ni ¯ 12 ] ( Al ¯ 1.5 Cr ¯ 1.5 ) with Z = 16. Similar tendency of composition evolution also appears in the PWA and CMSX series of SC superalloys. Typical TMS series of superalloys with prominent creep properties generally exhibit a moderate lattice misfit of γ/γ′ which could render alloys with appropriate particle size of cuboidal γ′ precipitates to acquire a maximum strength increment by precipitation strengthening mechanism. More importantly, the relationship between the lattice misfit (δ) of γ/γ′ and the creep rupture lifetime (t r ) of superalloys was then established, showing a linear correlation in the form of lgt r –lg\|δ\|3/2 at both conditions of 900 °C/392 MPa and 1100 °C/137 MPa. Combined with the lattice misfit, the cluster formula approach would provide a new way to modify or optimize the compositions of Ni-base superalloys for further improvement of creep property.
format	article
author	Chen Chen Qing Wang Chuang Dong Yu Zhang Honggang Dong
author_facet	Chen Chen Qing Wang Chuang Dong Yu Zhang Honggang Dong
author_sort	Chen Chen
title	Composition rules of Ni-base single crystal superalloys and its influence on creep properties via a cluster formula approach
title_short	Composition rules of Ni-base single crystal superalloys and its influence on creep properties via a cluster formula approach
title_full	Composition rules of Ni-base single crystal superalloys and its influence on creep properties via a cluster formula approach
title_fullStr	Composition rules of Ni-base single crystal superalloys and its influence on creep properties via a cluster formula approach
title_full_unstemmed	Composition rules of Ni-base single crystal superalloys and its influence on creep properties via a cluster formula approach
title_sort	composition rules of ni-base single crystal superalloys and its influence on creep properties via a cluster formula approach
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/7e4c9c2a50f44d55b9f7271c79f003b2
work_keys_str_mv	AT chenchen compositionrulesofnibasesinglecrystalsuperalloysanditsinfluenceoncreeppropertiesviaaclusterformulaapproach AT qingwang compositionrulesofnibasesinglecrystalsuperalloysanditsinfluenceoncreeppropertiesviaaclusterformulaapproach AT chuangdong compositionrulesofnibasesinglecrystalsuperalloysanditsinfluenceoncreeppropertiesviaaclusterformulaapproach AT yuzhang compositionrulesofnibasesinglecrystalsuperalloysanditsinfluenceoncreeppropertiesviaaclusterformulaapproach AT honggangdong compositionrulesofnibasesinglecrystalsuperalloysanditsinfluenceoncreeppropertiesviaaclusterformulaapproach
_version_	1718395290322468864

Composition rules of Ni-base single crystal superalloys and its influence on creep properties via a cluster formula approach

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