Total synthesis of atropurpuran
Polycyclic and caged molecules are common in nature but present challenging targets for synthesis. Here, the authors report a route to caged diterpene cores and apply to the total synthesis of atropurpuran, with oxidative dearomatization/intramolecular Diels-Alder cascade, aldol and ketyl-olefin cyc...
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Nature Portfolio
2016
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oai:doaj.org-article:7e7b6e2e09ec4b1aa11c31bd7ff945d72021-12-02T17:32:05ZTotal synthesis of atropurpuran10.1038/ncomms121832041-1723https://doaj.org/article/7e7b6e2e09ec4b1aa11c31bd7ff945d72016-07-01T00:00:00Zhttps://doi.org/10.1038/ncomms12183https://doaj.org/toc/2041-1723Polycyclic and caged molecules are common in nature but present challenging targets for synthesis. Here, the authors report a route to caged diterpene cores and apply to the total synthesis of atropurpuran, with oxidative dearomatization/intramolecular Diels-Alder cascade, aldol and ketyl-olefin cyclizations as key steps.Jing GongHuan ChenXiao-Yu LiuZhi-Xiu WangWei NieYong QinNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-6 (2016) |
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DOAJ |
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DOAJ |
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EN |
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Science Q |
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Science Q Jing Gong Huan Chen Xiao-Yu Liu Zhi-Xiu Wang Wei Nie Yong Qin Total synthesis of atropurpuran |
| description |
Polycyclic and caged molecules are common in nature but present challenging targets for synthesis. Here, the authors report a route to caged diterpene cores and apply to the total synthesis of atropurpuran, with oxidative dearomatization/intramolecular Diels-Alder cascade, aldol and ketyl-olefin cyclizations as key steps. |
| format |
article |
| author |
Jing Gong Huan Chen Xiao-Yu Liu Zhi-Xiu Wang Wei Nie Yong Qin |
| author_facet |
Jing Gong Huan Chen Xiao-Yu Liu Zhi-Xiu Wang Wei Nie Yong Qin |
| author_sort |
Jing Gong |
| title |
Total synthesis of atropurpuran |
| title_short |
Total synthesis of atropurpuran |
| title_full |
Total synthesis of atropurpuran |
| title_fullStr |
Total synthesis of atropurpuran |
| title_full_unstemmed |
Total synthesis of atropurpuran |
| title_sort |
total synthesis of atropurpuran |
| publisher |
Nature Portfolio |
| publishDate |
2016 |
| url |
https://doaj.org/article/7e7b6e2e09ec4b1aa11c31bd7ff945d7 |
| work_keys_str_mv |
AT jinggong totalsynthesisofatropurpuran AT huanchen totalsynthesisofatropurpuran AT xiaoyuliu totalsynthesisofatropurpuran AT zhixiuwang totalsynthesisofatropurpuran AT weinie totalsynthesisofatropurpuran AT yongqin totalsynthesisofatropurpuran |
| _version_ |
1718380378892271616 |