Total synthesis of atropurpuran

Polycyclic and caged molecules are common in nature but present challenging targets for synthesis. Here, the authors report a route to caged diterpene cores and apply to the total synthesis of atropurpuran, with oxidative dearomatization/intramolecular Diels-Alder cascade, aldol and ketyl-olefin cyc...

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Auteurs principaux: Jing Gong, Huan Chen, Xiao-Yu Liu, Zhi-Xiu Wang, Wei Nie, Yong Qin
Format: article
Langue:EN
Publié: Nature Portfolio 2016
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Accès en ligne:https://doaj.org/article/7e7b6e2e09ec4b1aa11c31bd7ff945d7
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