Platinum clusters with precise numbers of atoms for preparative-scale catalysis

The catalytic activity of a noble metal nanocluster is tied to its atomicity. Here, the authors report an atom-precise, fully scalable synthesis of platinum clusters from molecular ring precursors, and show that a variation of only one atom can dramatically change a cluster’s reactivity.

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Autores principales: Takane Imaoka, Yuki Akanuma, Naoki Haruta, Shogo Tsuchiya, Kentaro Ishihara, Takeshi Okayasu, Wang-Jae Chun, Masaki Takahashi, Kimihisa Yamamoto
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Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/7e858998a3b34573b8a6ad34db9b85ec
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spelling oai:doaj.org-article:7e858998a3b34573b8a6ad34db9b85ec2021-12-02T17:01:18ZPlatinum clusters with precise numbers of atoms for preparative-scale catalysis10.1038/s41467-017-00800-42041-1723https://doaj.org/article/7e858998a3b34573b8a6ad34db9b85ec2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00800-4https://doaj.org/toc/2041-1723The catalytic activity of a noble metal nanocluster is tied to its atomicity. Here, the authors report an atom-precise, fully scalable synthesis of platinum clusters from molecular ring precursors, and show that a variation of only one atom can dramatically change a cluster’s reactivity.Takane ImaokaYuki AkanumaNaoki HarutaShogo TsuchiyaKentaro IshiharaTakeshi OkayasuWang-Jae ChunMasaki TakahashiKimihisa YamamotoNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Takane Imaoka
Yuki Akanuma
Naoki Haruta
Shogo Tsuchiya
Kentaro Ishihara
Takeshi Okayasu
Wang-Jae Chun
Masaki Takahashi
Kimihisa Yamamoto
Platinum clusters with precise numbers of atoms for preparative-scale catalysis
description The catalytic activity of a noble metal nanocluster is tied to its atomicity. Here, the authors report an atom-precise, fully scalable synthesis of platinum clusters from molecular ring precursors, and show that a variation of only one atom can dramatically change a cluster’s reactivity.
format article
author Takane Imaoka
Yuki Akanuma
Naoki Haruta
Shogo Tsuchiya
Kentaro Ishihara
Takeshi Okayasu
Wang-Jae Chun
Masaki Takahashi
Kimihisa Yamamoto
author_facet Takane Imaoka
Yuki Akanuma
Naoki Haruta
Shogo Tsuchiya
Kentaro Ishihara
Takeshi Okayasu
Wang-Jae Chun
Masaki Takahashi
Kimihisa Yamamoto
author_sort Takane Imaoka
title Platinum clusters with precise numbers of atoms for preparative-scale catalysis
title_short Platinum clusters with precise numbers of atoms for preparative-scale catalysis
title_full Platinum clusters with precise numbers of atoms for preparative-scale catalysis
title_fullStr Platinum clusters with precise numbers of atoms for preparative-scale catalysis
title_full_unstemmed Platinum clusters with precise numbers of atoms for preparative-scale catalysis
title_sort platinum clusters with precise numbers of atoms for preparative-scale catalysis
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/7e858998a3b34573b8a6ad34db9b85ec
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