Platinum clusters with precise numbers of atoms for preparative-scale catalysis
The catalytic activity of a noble metal nanocluster is tied to its atomicity. Here, the authors report an atom-precise, fully scalable synthesis of platinum clusters from molecular ring precursors, and show that a variation of only one atom can dramatically change a cluster’s reactivity.
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Nature Portfolio
2017
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oai:doaj.org-article:7e858998a3b34573b8a6ad34db9b85ec2021-12-02T17:01:18ZPlatinum clusters with precise numbers of atoms for preparative-scale catalysis10.1038/s41467-017-00800-42041-1723https://doaj.org/article/7e858998a3b34573b8a6ad34db9b85ec2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00800-4https://doaj.org/toc/2041-1723The catalytic activity of a noble metal nanocluster is tied to its atomicity. Here, the authors report an atom-precise, fully scalable synthesis of platinum clusters from molecular ring precursors, and show that a variation of only one atom can dramatically change a cluster’s reactivity.Takane ImaokaYuki AkanumaNaoki HarutaShogo TsuchiyaKentaro IshiharaTakeshi OkayasuWang-Jae ChunMasaki TakahashiKimihisa YamamotoNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017) |
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Science Q Takane Imaoka Yuki Akanuma Naoki Haruta Shogo Tsuchiya Kentaro Ishihara Takeshi Okayasu Wang-Jae Chun Masaki Takahashi Kimihisa Yamamoto Platinum clusters with precise numbers of atoms for preparative-scale catalysis |
description |
The catalytic activity of a noble metal nanocluster is tied to its atomicity. Here, the authors report an atom-precise, fully scalable synthesis of platinum clusters from molecular ring precursors, and show that a variation of only one atom can dramatically change a cluster’s reactivity. |
format |
article |
author |
Takane Imaoka Yuki Akanuma Naoki Haruta Shogo Tsuchiya Kentaro Ishihara Takeshi Okayasu Wang-Jae Chun Masaki Takahashi Kimihisa Yamamoto |
author_facet |
Takane Imaoka Yuki Akanuma Naoki Haruta Shogo Tsuchiya Kentaro Ishihara Takeshi Okayasu Wang-Jae Chun Masaki Takahashi Kimihisa Yamamoto |
author_sort |
Takane Imaoka |
title |
Platinum clusters with precise numbers of atoms for preparative-scale catalysis |
title_short |
Platinum clusters with precise numbers of atoms for preparative-scale catalysis |
title_full |
Platinum clusters with precise numbers of atoms for preparative-scale catalysis |
title_fullStr |
Platinum clusters with precise numbers of atoms for preparative-scale catalysis |
title_full_unstemmed |
Platinum clusters with precise numbers of atoms for preparative-scale catalysis |
title_sort |
platinum clusters with precise numbers of atoms for preparative-scale catalysis |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/7e858998a3b34573b8a6ad34db9b85ec |
work_keys_str_mv |
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_version_ |
1718382154360029184 |