Tracking the Origin and Evolution of Diagenetic Fluids of Upper Jurassic Carbonate Rocks in the Zagros Thrust Fold Belt, NE-Iraq
Utilizing sophisticated tools in carbonate rocks is crucial to interpretating the origin and evolution of diagenetic fluids from the Upper Jurassic carbonate rocks along the Zagros thrust-fold Belt. The origin and evolution of the paleofluids utilizing in-situ strontium isotope ratios by high resolu...
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| Autores principales: | , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
MDPI AG
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/7ef253d645ae46019cb38ad9702d2519 |
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| Sumario: | Utilizing sophisticated tools in carbonate rocks is crucial to interpretating the origin and evolution of diagenetic fluids from the Upper Jurassic carbonate rocks along the Zagros thrust-fold Belt. The origin and evolution of the paleofluids utilizing in-situ strontium isotope ratios by high resolution laser ablation ICP-MS, integrated with stable isotopes, petrography and fieldwork are constrained. Due to the lack of information on the origin of the chemistry of the fluids, the cements that filled the Jurassic carbonate rocks were analysed from the fractures and pores. This allowed us to trace the origin of fluids along a diagenetic sequence, which is defined at the beginning from the sediment deposition (pristine facies). Based on petrography and geochemistry (oxygen-, carbon- and strontium-isotope compositions) two major diagenetic stages involving the fluids were identified. The initial stage, characterized by negative δ<sup>13</sup>C<sub>VPDB</sub> values (reaching −10.67‰), involved evaporated seawater deposited with the sediments, mixed with the input of freshwater. The second stage involved a mixture of meteoric water and hot fluids that precipitated as late diagenetic cements. The late diagenetic cements have higher depleted O–C isotope compositions compared to seawater. The diagenetic cements display a positive covariance and were associated with extra- δ<sup>13</sup>C<sub>VPDB</sub> and δ<sup>18</sup>O<sub>VPDB</sub> values (−12.87‰ to −0.82‰ for δ<sup>18</sup>O<sub>VPDB</sub> and −11.66‰ to −1.40‰ for δ<sup>13</sup>C<sub>VPDB</sub> respectively). The distinction between seawater and the secondary fluids is also evident in the <sup>87</sup>Sr/<sup>86</sup>Sr of the host limestone versus cements. The limestones have <sup>87</sup>Sr/<sup>86</sup>Sr up to 0.72859, indicative of riverine input, while the cements have <sup>87</sup>Sr/<sup>86</sup>Sr of (0.70772), indicative of hot fluid circulation interacting with meteoric water during late diagenesis. |
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