Photo-tautomerization of acetaldehyde as a photochemical source of formic acid in the troposphere

The concentration of formic acid in Earth’s atmosphere is under-predicted by atmospheric models. Here the authors show that acetaldehyde photo-tautomerizes to vinyl alcohol under tropospheric conditions, with subsequent oxidation via OH radicals supplying up to 60% of total modeled formic acid produ...

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Autores principales:	Miranda F. Shaw, Bálint Sztáray, Lisa K. Whalley, Dwayne E. Heard, Dylan B. Millet, Meredith J. T. Jordan, David L. Osborn, Scott H. Kable
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/7f096c4e0fca4600b0291c13acfeec05
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spelling	oai:doaj.org-article:7f096c4e0fca4600b0291c13acfeec052021-12-02T14:40:54ZPhoto-tautomerization of acetaldehyde as a photochemical source of formic acid in the troposphere10.1038/s41467-018-04824-22041-1723https://doaj.org/article/7f096c4e0fca4600b0291c13acfeec052018-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04824-2https://doaj.org/toc/2041-1723The concentration of formic acid in Earth’s atmosphere is under-predicted by atmospheric models. Here the authors show that acetaldehyde photo-tautomerizes to vinyl alcohol under tropospheric conditions, with subsequent oxidation via OH radicals supplying up to 60% of total modeled formic acid production over oceans.Miranda F. ShawBálint SztárayLisa K. WhalleyDwayne E. HeardDylan B. MilletMeredith J. T. JordanDavid L. OsbornScott H. KableNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Miranda F. Shaw Bálint Sztáray Lisa K. Whalley Dwayne E. Heard Dylan B. Millet Meredith J. T. Jordan David L. Osborn Scott H. Kable Photo-tautomerization of acetaldehyde as a photochemical source of formic acid in the troposphere
description	The concentration of formic acid in Earth’s atmosphere is under-predicted by atmospheric models. Here the authors show that acetaldehyde photo-tautomerizes to vinyl alcohol under tropospheric conditions, with subsequent oxidation via OH radicals supplying up to 60% of total modeled formic acid production over oceans.
format	article
author	Miranda F. Shaw Bálint Sztáray Lisa K. Whalley Dwayne E. Heard Dylan B. Millet Meredith J. T. Jordan David L. Osborn Scott H. Kable
author_facet	Miranda F. Shaw Bálint Sztáray Lisa K. Whalley Dwayne E. Heard Dylan B. Millet Meredith J. T. Jordan David L. Osborn Scott H. Kable
author_sort	Miranda F. Shaw
title	Photo-tautomerization of acetaldehyde as a photochemical source of formic acid in the troposphere
title_short	Photo-tautomerization of acetaldehyde as a photochemical source of formic acid in the troposphere
title_full	Photo-tautomerization of acetaldehyde as a photochemical source of formic acid in the troposphere
title_fullStr	Photo-tautomerization of acetaldehyde as a photochemical source of formic acid in the troposphere
title_full_unstemmed	Photo-tautomerization of acetaldehyde as a photochemical source of formic acid in the troposphere
title_sort	photo-tautomerization of acetaldehyde as a photochemical source of formic acid in the troposphere
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/7f096c4e0fca4600b0291c13acfeec05
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Photo-tautomerization of acetaldehyde as a photochemical source of formic acid in the troposphere

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