Preparation and Characterization of Electrospun Nanofiber of Poly (Vinyl Alcohol) and Cellulose Nanocrystals

In this study Poly vinyl alcohol (PVA) and cellulose nanocrysrals (CNC) composite nanofibers were prepared by electrospinning process. To dissolve PVA, the deionized water was used due to environmental friendly of PVA. The design of experiments (DOE) was done by the Taguchi method using the Minitab...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Hadi Ashtari, Mehdi Jonoobi, Maryam Yousefzadeh, Yahya Hamzeh
Formato:	article
Lenguaje:	FA
Publicado:	Regional Information Center for Science and Technology (RICeST) 2018
Materias:	Nanocomposites Polyvinyl Alcohol Cellulose Nanocrystal Nanofibers Electrospinning Forestry SD1-669.5
Acceso en línea:	https://doaj.org/article/8005f4fb9e734379b5777c96d49608fd
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:8005f4fb9e734379b5777c96d49608fd
record_format	dspace
spelling	oai:doaj.org-article:8005f4fb9e734379b5777c96d49608fd2021-12-02T07:31:01ZPreparation and Characterization of Electrospun Nanofiber of Poly (Vinyl Alcohol) and Cellulose Nanocrystals1735-09132383-112X10.22092/ijwpr.2018.121871.1475https://doaj.org/article/8005f4fb9e734379b5777c96d49608fd2018-11-01T00:00:00Zhttp://ijwpr.areeo.ac.ir/article_117036_ca1b98aabbca12eea36bbf22cb8bf338.pdfhttps://doaj.org/toc/1735-0913https://doaj.org/toc/2383-112XIn this study Poly vinyl alcohol (PVA) and cellulose nanocrysrals (CNC) composite nanofibers were prepared by electrospinning process. To dissolve PVA, the deionized water was used due to environmental friendly of PVA. The design of experiments (DOE) was done by the Taguchi method using the Minitab for optimization of electrospinning. Polymer concentration was determined in 4, 6, 8 and 10% by solvent weight. Bead-free fibers were produced in 8% PVA concentration. CNC were added to polymer in 0.5, 1, 1.5 and 2% by PVA weight and DOE was applied for Needle to collector distance (cm), polymer concentration (%), polymer feed rate (mh/hr.) and applied voltage (Kv) were defined as variables, again to reach the thinnest fibers. Nanocomposites were soaked in GA 50% concentration for 48 hrs. to prevent nanocomposites decomposition. SEM and FESEM were used for morphological characterization. Diameter of the fibers was analyzed by Image software. Tensile, Modulus of Elasticity (MOE), Tension, Porosity, swelling and dissolving of nanocomposites were examined. Chemical reactions were traced by FTIR. Fibers with 87±16 nm in diameter were achieved in 0.5% CNC, 22 KV, 0.3 ml/hr. and 20 cm. Swelling and and solubility of nanocomposites were significantly improved by GA. FTIR spectra shows hemiacetal bounds produced during GA soaking. MOE and tensile were improved by CNC addition meanwhile tension and porosity were decreased. Same results were obtained for GA soaked nanocomposites.Hadi AshtariMehdi JonoobiMaryam YousefzadehYahya HamzehRegional Information Center for Science and Technology (RICeST)articleNanocompositesPolyvinyl AlcoholCellulose NanocrystalNanofibersElectrospinningForestrySD1-669.5FAتحقیقات علوم چوب و کاغذ ایران, Vol 33, Iss 3, Pp 438-452 (2018)
institution	DOAJ
collection	DOAJ
language	FA
topic	Nanocomposites Polyvinyl Alcohol Cellulose Nanocrystal Nanofibers Electrospinning Forestry SD1-669.5
spellingShingle	Nanocomposites Polyvinyl Alcohol Cellulose Nanocrystal Nanofibers Electrospinning Forestry SD1-669.5 Hadi Ashtari Mehdi Jonoobi Maryam Yousefzadeh Yahya Hamzeh Preparation and Characterization of Electrospun Nanofiber of Poly (Vinyl Alcohol) and Cellulose Nanocrystals
description	In this study Poly vinyl alcohol (PVA) and cellulose nanocrysrals (CNC) composite nanofibers were prepared by electrospinning process. To dissolve PVA, the deionized water was used due to environmental friendly of PVA. The design of experiments (DOE) was done by the Taguchi method using the Minitab for optimization of electrospinning. Polymer concentration was determined in 4, 6, 8 and 10% by solvent weight. Bead-free fibers were produced in 8% PVA concentration. CNC were added to polymer in 0.5, 1, 1.5 and 2% by PVA weight and DOE was applied for Needle to collector distance (cm), polymer concentration (%), polymer feed rate (mh/hr.) and applied voltage (Kv) were defined as variables, again to reach the thinnest fibers. Nanocomposites were soaked in GA 50% concentration for 48 hrs. to prevent nanocomposites decomposition. SEM and FESEM were used for morphological characterization. Diameter of the fibers was analyzed by Image software. Tensile, Modulus of Elasticity (MOE), Tension, Porosity, swelling and dissolving of nanocomposites were examined. Chemical reactions were traced by FTIR. Fibers with 87±16 nm in diameter were achieved in 0.5% CNC, 22 KV, 0.3 ml/hr. and 20 cm. Swelling and and solubility of nanocomposites were significantly improved by GA. FTIR spectra shows hemiacetal bounds produced during GA soaking. MOE and tensile were improved by CNC addition meanwhile tension and porosity were decreased. Same results were obtained for GA soaked nanocomposites.
format	article
author	Hadi Ashtari Mehdi Jonoobi Maryam Yousefzadeh Yahya Hamzeh
author_facet	Hadi Ashtari Mehdi Jonoobi Maryam Yousefzadeh Yahya Hamzeh
author_sort	Hadi Ashtari
title	Preparation and Characterization of Electrospun Nanofiber of Poly (Vinyl Alcohol) and Cellulose Nanocrystals
title_short	Preparation and Characterization of Electrospun Nanofiber of Poly (Vinyl Alcohol) and Cellulose Nanocrystals
title_full	Preparation and Characterization of Electrospun Nanofiber of Poly (Vinyl Alcohol) and Cellulose Nanocrystals
title_fullStr	Preparation and Characterization of Electrospun Nanofiber of Poly (Vinyl Alcohol) and Cellulose Nanocrystals
title_full_unstemmed	Preparation and Characterization of Electrospun Nanofiber of Poly (Vinyl Alcohol) and Cellulose Nanocrystals
title_sort	preparation and characterization of electrospun nanofiber of poly (vinyl alcohol) and cellulose nanocrystals
publisher	Regional Information Center for Science and Technology (RICeST)
publishDate	2018
url	https://doaj.org/article/8005f4fb9e734379b5777c96d49608fd
work_keys_str_mv	AT hadiashtari preparationandcharacterizationofelectrospunnanofiberofpolyvinylalcoholandcellulosenanocrystals AT mehdijonoobi preparationandcharacterizationofelectrospunnanofiberofpolyvinylalcoholandcellulosenanocrystals AT maryamyousefzadeh preparationandcharacterizationofelectrospunnanofiberofpolyvinylalcoholandcellulosenanocrystals AT yahyahamzeh preparationandcharacterizationofelectrospunnanofiberofpolyvinylalcoholandcellulosenanocrystals
_version_	1718399411838517248

Preparation and Characterization of Electrospun Nanofiber of Poly (Vinyl Alcohol) and Cellulose Nanocrystals

Ejemplares similares