NHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins

Chiral 1,4-dienes are versatile building blocks in asymmetric synthesis, therefore their production is highly sought after. Here, the authors report an efficient enantioselective cross-hydroalkenylation of cyclic 1,3-dienes and terminal olefins affording chiral 1,4-dienes by using a chiral NHC-Ni(al...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Yang Chen, Liang Dang, Chun-Yu Ho
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/802d8014acf847eb98319024b48d66b0
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:802d8014acf847eb98319024b48d66b0
record_format	dspace
spelling	oai:doaj.org-article:802d8014acf847eb98319024b48d66b02021-12-02T14:42:14ZNHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins10.1038/s41467-020-16139-22041-1723https://doaj.org/article/802d8014acf847eb98319024b48d66b02020-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16139-2https://doaj.org/toc/2041-1723Chiral 1,4-dienes are versatile building blocks in asymmetric synthesis, therefore their production is highly sought after. Here, the authors report an efficient enantioselective cross-hydroalkenylation of cyclic 1,3-dienes and terminal olefins affording chiral 1,4-dienes by using a chiral NHC-Ni(allyl)]BArF catalyst.Yang ChenLiang DangChun-Yu HoNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-6 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yang Chen Liang Dang Chun-Yu Ho NHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins
description	Chiral 1,4-dienes are versatile building blocks in asymmetric synthesis, therefore their production is highly sought after. Here, the authors report an efficient enantioselective cross-hydroalkenylation of cyclic 1,3-dienes and terminal olefins affording chiral 1,4-dienes by using a chiral NHC-Ni(allyl)]BArF catalyst.
format	article
author	Yang Chen Liang Dang Chun-Yu Ho
author_facet	Yang Chen Liang Dang Chun-Yu Ho
author_sort	Yang Chen
title	NHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins
title_short	NHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins
title_full	NHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins
title_fullStr	NHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins
title_full_unstemmed	NHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins
title_sort	nhc-ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/802d8014acf847eb98319024b48d66b0
work_keys_str_mv	AT yangchen nhcnicatalyzedenantioselectivesynthesisof14dienesbycrosshydroalkenylationofcyclic13dienesandheterosubstitutedterminalolefins AT liangdang nhcnicatalyzedenantioselectivesynthesisof14dienesbycrosshydroalkenylationofcyclic13dienesandheterosubstitutedterminalolefins AT chunyuho nhcnicatalyzedenantioselectivesynthesisof14dienesbycrosshydroalkenylationofcyclic13dienesandheterosubstitutedterminalolefins
_version_	1718389761526202368

NHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins

Ejemplares similares