Oxidative Degradation of Pharmaceuticals: The Role of Tetrapyrrole-Based Catalysts

Nowadays, society’s widespread consumption of pharmaceutical drugs and the consequent accumulation of such compounds or their metabolites in effluents requires the development of efficient strategies and systems that lead to their effective degradation. This can be done through oxidative processes,...

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Autores principales:	Giusi Piccirillo, Rafael T. Aroso, Fábio M. S. Rodrigues, Rui M. B. Carrilho, Sara M. A. Pinto, Mário J. F. Calvete, Mariette M. Pereira
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	tetrapyrrolic macrocycle porphyrin phthalocyanine antibiotics pharmaceuticals degradation Chemical technology TP1-1185 Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/80b521af5dca44f8bc49655d9e8b37fc
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spelling	oai:doaj.org-article:80b521af5dca44f8bc49655d9e8b37fc2021-11-25T17:06:00ZOxidative Degradation of Pharmaceuticals: The Role of Tetrapyrrole-Based Catalysts10.3390/catal111113352073-4344https://doaj.org/article/80b521af5dca44f8bc49655d9e8b37fc2021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4344/11/11/1335https://doaj.org/toc/2073-4344Nowadays, society’s widespread consumption of pharmaceutical drugs and the consequent accumulation of such compounds or their metabolites in effluents requires the development of efficient strategies and systems that lead to their effective degradation. This can be done through oxidative processes, in which tetrapyrrolic macrocycles (porphyrins, phthalocyanines) deserve special attention since they are among the most promising degradation catalysts. This paper presents a review of the literature over the past ten years on the major advances made in the development of oxidation processes of pharmaceuticals in aqueous solutions using tetrapyrrole-based catalysts. The review presents a brief discussion of the mechanisms involved in these oxidative processes and is organized by the degradation of families of pharmaceutical compounds, namely antibiotics, analgesics and neurological drugs, among others. For each family, a critical analysis and discussion of the fundamental roles of tetrapyrrolic macrocycles are presented, regarding both photochemical degradative processes and direct oxidative chemical degradation.Giusi PiccirilloRafael T. ArosoFábio M. S. RodriguesRui M. B. CarrilhoSara M. A. PintoMário J. F. CalveteMariette M. PereiraMDPI AGarticletetrapyrrolic macrocycleporphyrinphthalocyanineantibioticspharmaceuticalsdegradationChemical technologyTP1-1185ChemistryQD1-999ENCatalysts, Vol 11, Iss 1335, p 1335 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	tetrapyrrolic macrocycle porphyrin phthalocyanine antibiotics pharmaceuticals degradation Chemical technology TP1-1185 Chemistry QD1-999
spellingShingle	tetrapyrrolic macrocycle porphyrin phthalocyanine antibiotics pharmaceuticals degradation Chemical technology TP1-1185 Chemistry QD1-999 Giusi Piccirillo Rafael T. Aroso Fábio M. S. Rodrigues Rui M. B. Carrilho Sara M. A. Pinto Mário J. F. Calvete Mariette M. Pereira Oxidative Degradation of Pharmaceuticals: The Role of Tetrapyrrole-Based Catalysts
description	Nowadays, society’s widespread consumption of pharmaceutical drugs and the consequent accumulation of such compounds or their metabolites in effluents requires the development of efficient strategies and systems that lead to their effective degradation. This can be done through oxidative processes, in which tetrapyrrolic macrocycles (porphyrins, phthalocyanines) deserve special attention since they are among the most promising degradation catalysts. This paper presents a review of the literature over the past ten years on the major advances made in the development of oxidation processes of pharmaceuticals in aqueous solutions using tetrapyrrole-based catalysts. The review presents a brief discussion of the mechanisms involved in these oxidative processes and is organized by the degradation of families of pharmaceutical compounds, namely antibiotics, analgesics and neurological drugs, among others. For each family, a critical analysis and discussion of the fundamental roles of tetrapyrrolic macrocycles are presented, regarding both photochemical degradative processes and direct oxidative chemical degradation.
format	article
author	Giusi Piccirillo Rafael T. Aroso Fábio M. S. Rodrigues Rui M. B. Carrilho Sara M. A. Pinto Mário J. F. Calvete Mariette M. Pereira
author_facet	Giusi Piccirillo Rafael T. Aroso Fábio M. S. Rodrigues Rui M. B. Carrilho Sara M. A. Pinto Mário J. F. Calvete Mariette M. Pereira
author_sort	Giusi Piccirillo
title	Oxidative Degradation of Pharmaceuticals: The Role of Tetrapyrrole-Based Catalysts
title_short	Oxidative Degradation of Pharmaceuticals: The Role of Tetrapyrrole-Based Catalysts
title_full	Oxidative Degradation of Pharmaceuticals: The Role of Tetrapyrrole-Based Catalysts
title_fullStr	Oxidative Degradation of Pharmaceuticals: The Role of Tetrapyrrole-Based Catalysts
title_full_unstemmed	Oxidative Degradation of Pharmaceuticals: The Role of Tetrapyrrole-Based Catalysts
title_sort	oxidative degradation of pharmaceuticals: the role of tetrapyrrole-based catalysts
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/80b521af5dca44f8bc49655d9e8b37fc
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Oxidative Degradation of Pharmaceuticals: The Role of Tetrapyrrole-Based Catalysts

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