Concurrent and orthogonal gold(I) and ruthenium(II) catalysis inside living cells
Transition-metal catalysis in living cells poses numerous challenges in terms of biocompatibility, and complex stability and reactivity. Here, the authors report a bioorthogonal gold-catalyzed C-C coupling reaction, occurring in living mammalian cells, even in parallel with a ruthenium-catalyzed dea...
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Auteurs principaux: | , , , , |
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Format: | article |
Langue: | EN |
Publié: |
Nature Portfolio
2018
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Accès en ligne: | https://doaj.org/article/819f51fd824a4edb97a24c6e05c92ace |
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Résumé: | Transition-metal catalysis in living cells poses numerous challenges in terms of biocompatibility, and complex stability and reactivity. Here, the authors report a bioorthogonal gold-catalyzed C-C coupling reaction, occurring in living mammalian cells, even in parallel with a ruthenium-catalyzed deallylation reaction. |
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