Directed nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes

Few methods exist to add a carbon and nitrogen atom across an unfunctionalized alkene. Here the authors show a method to regio- and diastereoselectively add aryl and amino groups to terminal and internal alkenes, via nickel catalysis and a removable directing group.

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Autores principales:	Leipeng Xie, Shenghao Wang, Lanlan Zhang, Lei Zhao, Chun Luo, Linping Mu, Xiuguang Wang, Chao Wang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/81d9ed20756849d89abf2dee50a2638c
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spelling	oai:doaj.org-article:81d9ed20756849d89abf2dee50a2638c2021-11-08T11:12:41ZDirected nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes10.1038/s41467-021-26527-x2041-1723https://doaj.org/article/81d9ed20756849d89abf2dee50a2638c2021-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-26527-xhttps://doaj.org/toc/2041-1723Few methods exist to add a carbon and nitrogen atom across an unfunctionalized alkene. Here the authors show a method to regio- and diastereoselectively add aryl and amino groups to terminal and internal alkenes, via nickel catalysis and a removable directing group.Leipeng XieShenghao WangLanlan ZhangLei ZhaoChun LuoLinping MuXiuguang WangChao WangNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Leipeng Xie Shenghao Wang Lanlan Zhang Lei Zhao Chun Luo Linping Mu Xiuguang Wang Chao Wang Directed nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes
description	Few methods exist to add a carbon and nitrogen atom across an unfunctionalized alkene. Here the authors show a method to regio- and diastereoselectively add aryl and amino groups to terminal and internal alkenes, via nickel catalysis and a removable directing group.
format	article
author	Leipeng Xie Shenghao Wang Lanlan Zhang Lei Zhao Chun Luo Linping Mu Xiuguang Wang Chao Wang
author_facet	Leipeng Xie Shenghao Wang Lanlan Zhang Lei Zhao Chun Luo Linping Mu Xiuguang Wang Chao Wang
author_sort	Leipeng Xie
title	Directed nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes
title_short	Directed nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes
title_full	Directed nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes
title_fullStr	Directed nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes
title_full_unstemmed	Directed nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes
title_sort	directed nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/81d9ed20756849d89abf2dee50a2638c
work_keys_str_mv	AT leipengxie directednickelcatalyzedregioanddiastereoselectivearylaminationofunactivatedalkenes AT shenghaowang directednickelcatalyzedregioanddiastereoselectivearylaminationofunactivatedalkenes AT lanlanzhang directednickelcatalyzedregioanddiastereoselectivearylaminationofunactivatedalkenes AT leizhao directednickelcatalyzedregioanddiastereoselectivearylaminationofunactivatedalkenes AT chunluo directednickelcatalyzedregioanddiastereoselectivearylaminationofunactivatedalkenes AT linpingmu directednickelcatalyzedregioanddiastereoselectivearylaminationofunactivatedalkenes AT xiuguangwang directednickelcatalyzedregioanddiastereoselectivearylaminationofunactivatedalkenes AT chaowang directednickelcatalyzedregioanddiastereoselectivearylaminationofunactivatedalkenes
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Directed nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes

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