Equilibrium and non-equilibrium furanose selection in the ribose isomerisation network

Furanose species have a key role in the chemistry of life despite their instability over pyranose ones. The authors, through NMR characterization of the anomeric ratios at equilibrium and a non-equilibrium theoretical treatment, show that a steady temperature gradient, at temperatures relevant to th...

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Autores principales:	Avinash Vicholous Dass, Thomas Georgelin, Frances Westall, Frédéric Foucher, Paolo De Los Rios, Daniel Maria Busiello, Shiling Liang, Francesco Piazza
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/8254f1db034e4302a888aff6171252c2
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spelling	oai:doaj.org-article:8254f1db034e4302a888aff6171252c22021-12-02T15:43:06ZEquilibrium and non-equilibrium furanose selection in the ribose isomerisation network10.1038/s41467-021-22818-52041-1723https://doaj.org/article/8254f1db034e4302a888aff6171252c22021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22818-5https://doaj.org/toc/2041-1723Furanose species have a key role in the chemistry of life despite their instability over pyranose ones. The authors, through NMR characterization of the anomeric ratios at equilibrium and a non-equilibrium theoretical treatment, show that a steady temperature gradient, at temperatures relevant to the early Earth, favors furanose over pyranose isomers.Avinash Vicholous DassThomas GeorgelinFrances WestallFrédéric FoucherPaolo De Los RiosDaniel Maria BusielloShiling LiangFrancesco PiazzaNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Avinash Vicholous Dass Thomas Georgelin Frances Westall Frédéric Foucher Paolo De Los Rios Daniel Maria Busiello Shiling Liang Francesco Piazza Equilibrium and non-equilibrium furanose selection in the ribose isomerisation network
description	Furanose species have a key role in the chemistry of life despite their instability over pyranose ones. The authors, through NMR characterization of the anomeric ratios at equilibrium and a non-equilibrium theoretical treatment, show that a steady temperature gradient, at temperatures relevant to the early Earth, favors furanose over pyranose isomers.
format	article
author	Avinash Vicholous Dass Thomas Georgelin Frances Westall Frédéric Foucher Paolo De Los Rios Daniel Maria Busiello Shiling Liang Francesco Piazza
author_facet	Avinash Vicholous Dass Thomas Georgelin Frances Westall Frédéric Foucher Paolo De Los Rios Daniel Maria Busiello Shiling Liang Francesco Piazza
author_sort	Avinash Vicholous Dass
title	Equilibrium and non-equilibrium furanose selection in the ribose isomerisation network
title_short	Equilibrium and non-equilibrium furanose selection in the ribose isomerisation network
title_full	Equilibrium and non-equilibrium furanose selection in the ribose isomerisation network
title_fullStr	Equilibrium and non-equilibrium furanose selection in the ribose isomerisation network
title_full_unstemmed	Equilibrium and non-equilibrium furanose selection in the ribose isomerisation network
title_sort	equilibrium and non-equilibrium furanose selection in the ribose isomerisation network
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/8254f1db034e4302a888aff6171252c2
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Equilibrium and non-equilibrium furanose selection in the ribose isomerisation network

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