Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition

The activity of electrocatalysts exhibits a strong dependence on their electronic structures. Here, the authors manipulate the eg filling of perovskite cobaltite LaCoO3nanoparticles by changing particle size and show improved oxygen evolution activity with increased numbers of surface high-spin coba...

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Autores principales: Shiming Zhou, Xianbing Miao, Xu Zhao, Chao Ma, Yuhao Qiu, Zhenpeng Hu, Jiyin Zhao, Lei Shi, Jie Zeng
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/82763ab7e4d74ba087491b8d769dbef7
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spelling oai:doaj.org-article:82763ab7e4d74ba087491b8d769dbef72021-12-02T17:31:51ZEngineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition10.1038/ncomms115102041-1723https://doaj.org/article/82763ab7e4d74ba087491b8d769dbef72016-05-01T00:00:00Zhttps://doi.org/10.1038/ncomms11510https://doaj.org/toc/2041-1723The activity of electrocatalysts exhibits a strong dependence on their electronic structures. Here, the authors manipulate the eg filling of perovskite cobaltite LaCoO3nanoparticles by changing particle size and show improved oxygen evolution activity with increased numbers of surface high-spin cobalt ions.Shiming ZhouXianbing MiaoXu ZhaoChao MaYuhao QiuZhenpeng HuJiyin ZhaoLei ShiJie ZengNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Shiming Zhou
Xianbing Miao
Xu Zhao
Chao Ma
Yuhao Qiu
Zhenpeng Hu
Jiyin Zhao
Lei Shi
Jie Zeng
Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition
description The activity of electrocatalysts exhibits a strong dependence on their electronic structures. Here, the authors manipulate the eg filling of perovskite cobaltite LaCoO3nanoparticles by changing particle size and show improved oxygen evolution activity with increased numbers of surface high-spin cobalt ions.
format article
author Shiming Zhou
Xianbing Miao
Xu Zhao
Chao Ma
Yuhao Qiu
Zhenpeng Hu
Jiyin Zhao
Lei Shi
Jie Zeng
author_facet Shiming Zhou
Xianbing Miao
Xu Zhao
Chao Ma
Yuhao Qiu
Zhenpeng Hu
Jiyin Zhao
Lei Shi
Jie Zeng
author_sort Shiming Zhou
title Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition
title_short Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition
title_full Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition
title_fullStr Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition
title_full_unstemmed Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition
title_sort engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition
publisher Nature Portfolio
publishDate 2016
url https://doaj.org/article/82763ab7e4d74ba087491b8d769dbef7
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