Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process
Water pollution with petroleum compounds is one of the most important environmental problems in oil-rich countries, due to its adverse effect on soil, water, and human beings. The hydrophilic hollow fiber membranes were produced by polymer blending of polyamide imide and sulfonated poly ether ether...
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Water and Wastewater Consulting Engineers Research Development
2021
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oai:doaj.org-article:82bc1f8facc145c2aee431c4856e10582021-11-20T08:16:50ZModification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process1024-59362383-090510.22093/wwj.2021.259417.3083https://doaj.org/article/82bc1f8facc145c2aee431c4856e10582021-10-01T00:00:00Zhttp://www.wwjournal.ir/article_135610_4d1632b2a988514f1f314f26c95c6db2.pdfhttps://doaj.org/toc/1024-5936https://doaj.org/toc/2383-0905Water pollution with petroleum compounds is one of the most important environmental problems in oil-rich countries, due to its adverse effect on soil, water, and human beings. The hydrophilic hollow fiber membranes were produced by polymer blending of polyamide imide and sulfonated poly ether ether ketone. Membrane structure and function were investigated by field emission scanning electron microscopy analysis, N2 permeation, overall porosity, collapse pressure, water contact angle, pure water flux tests. A membrane bioreactor system was used for oily wastewater treatment. From FESEM, a more open structure with larger finger-like was observed by increasing the PAI / SPEEK ratio. Using the PAI / SPEEK ratio of 85/15, the water contact angle of the membrane was decreased from 74° to 58° which showed a significant hydrophilicity improvement. From compaction test, pure water flux of the membranes showed a gradual decrease during 2.5 h and then reached a steady state with minimal changes. During a period of about 5 hours of the oil separation through the MBR process, the plain PAI membrane and the blend PAI-SPEEK membrane showed water flux reduction of about 35% and 21%, respectively. Under 5 bar transmembrane pressure and the addition of 30 mg/l of oil spill eater (OSEII) enzyme, the oil concentration decreased from 36 ppm to 1.2 ppm in the wastewater, which represents the oil removal efficiency of about 97%. In this work, the optimum state for oil removal was obtained in terms of adding OSEII and aeration.Ahmad JohariAmir MansourizadehDariush EmadzadehWater and Wastewater Consulting Engineers Research Developmentarticleblend hollow fiber membranepolyamide imidesulfonated poly (ether ether ketone)membrane bioreactoroily wastewater treatmentTechnologyTWater supply for domestic and industrial purposesTD201-500Sewage collection and disposal systems. SewerageTD511-780ENFAآب و فاضلاب, Vol 32, Iss 4, Pp 1-20 (2021) |
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EN FA |
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blend hollow fiber membrane polyamide imide sulfonated poly (ether ether ketone) membrane bioreactor oily wastewater treatment Technology T Water supply for domestic and industrial purposes TD201-500 Sewage collection and disposal systems. Sewerage TD511-780 |
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blend hollow fiber membrane polyamide imide sulfonated poly (ether ether ketone) membrane bioreactor oily wastewater treatment Technology T Water supply for domestic and industrial purposes TD201-500 Sewage collection and disposal systems. Sewerage TD511-780 Ahmad Johari Amir Mansourizadeh Dariush Emadzadeh Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process |
description |
Water pollution with petroleum compounds is one of the most important environmental problems in oil-rich countries, due to its adverse effect on soil, water, and human beings. The hydrophilic hollow fiber membranes were produced by polymer blending of polyamide imide and sulfonated poly ether ether ketone. Membrane structure and function were investigated by field emission scanning electron microscopy analysis, N2 permeation, overall porosity, collapse pressure, water contact angle, pure water flux tests. A membrane bioreactor system was used for oily wastewater treatment. From FESEM, a more open structure with larger finger-like was observed by increasing the PAI / SPEEK ratio. Using the PAI / SPEEK ratio of 85/15, the water contact angle of the membrane was decreased from 74° to 58° which showed a significant hydrophilicity improvement. From compaction test, pure water flux of the membranes showed a gradual decrease during 2.5 h and then reached a steady state with minimal changes. During a period of about 5 hours of the oil separation through the MBR process, the plain PAI membrane and the blend PAI-SPEEK membrane showed water flux reduction of about 35% and 21%, respectively. Under 5 bar transmembrane pressure and the addition of 30 mg/l of oil spill eater (OSEII) enzyme, the oil concentration decreased from 36 ppm to 1.2 ppm in the wastewater, which represents the oil removal efficiency of about 97%. In this work, the optimum state for oil removal was obtained in terms of adding OSEII and aeration. |
format |
article |
author |
Ahmad Johari Amir Mansourizadeh Dariush Emadzadeh |
author_facet |
Ahmad Johari Amir Mansourizadeh Dariush Emadzadeh |
author_sort |
Ahmad Johari |
title |
Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process |
title_short |
Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process |
title_full |
Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process |
title_fullStr |
Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process |
title_full_unstemmed |
Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process |
title_sort |
modification and enhancement of hydrophilicity of hollow fiber polymer alloy membranes with sulfonated poly (ether ether ketone) for the treatment of oil effluents using the membrane bioreactor process |
publisher |
Water and Wastewater Consulting Engineers Research Development |
publishDate |
2021 |
url |
https://doaj.org/article/82bc1f8facc145c2aee431c4856e1058 |
work_keys_str_mv |
AT ahmadjohari modificationandenhancementofhydrophilicityofhollowfiberpolymeralloymembraneswithsulfonatedpolyetheretherketoneforthetreatmentofoileffluentsusingthemembranebioreactorprocess AT amirmansourizadeh modificationandenhancementofhydrophilicityofhollowfiberpolymeralloymembraneswithsulfonatedpolyetheretherketoneforthetreatmentofoileffluentsusingthemembranebioreactorprocess AT dariushemadzadeh modificationandenhancementofhydrophilicityofhollowfiberpolymeralloymembraneswithsulfonatedpolyetheretherketoneforthetreatmentofoileffluentsusingthemembranebioreactorprocess |
_version_ |
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