Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process

Water pollution with petroleum compounds is one of the most important environmental problems in oil-rich countries, due to its adverse effect on soil, water, and human beings. The hydrophilic hollow fiber membranes were produced by polymer blending of polyamide imide and sulfonated poly ether ether...

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Autores principales: Ahmad Johari, Amir Mansourizadeh, Dariush Emadzadeh
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Publicado: Water and Wastewater Consulting Engineers Research Development 2021
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spelling oai:doaj.org-article:82bc1f8facc145c2aee431c4856e10582021-11-20T08:16:50ZModification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process1024-59362383-090510.22093/wwj.2021.259417.3083https://doaj.org/article/82bc1f8facc145c2aee431c4856e10582021-10-01T00:00:00Zhttp://www.wwjournal.ir/article_135610_4d1632b2a988514f1f314f26c95c6db2.pdfhttps://doaj.org/toc/1024-5936https://doaj.org/toc/2383-0905Water pollution with petroleum compounds is one of the most important environmental problems in oil-rich countries, due to its adverse effect on soil, water, and human beings. The hydrophilic hollow fiber membranes were produced by polymer blending of polyamide imide and sulfonated poly ether ether ketone. Membrane structure and function were investigated by field emission scanning electron microscopy analysis, N2 permeation, overall porosity, collapse pressure, water contact angle, pure water flux tests. A membrane bioreactor system was used for oily wastewater treatment. From FESEM, a more open structure with larger finger-like was observed by increasing the PAI / SPEEK ratio. Using the PAI / SPEEK ratio of 85/15, the water contact angle of the membrane was decreased from 74° to 58° which showed a significant hydrophilicity improvement. From compaction test, pure water flux of the membranes showed a gradual decrease during 2.5 h and then reached a steady state with minimal changes. During a period of about 5 hours of the oil separation through the MBR process, the plain PAI membrane and the blend PAI-SPEEK membrane showed water flux reduction of about 35% and 21%, respectively. Under 5 bar transmembrane pressure and the addition of 30 mg/l of oil spill eater (OSEII) enzyme, the oil concentration decreased from 36 ppm to 1.2 ppm in the wastewater, which represents the oil removal efficiency of about 97%. In this work, the optimum state for oil removal was obtained in terms of adding OSEII and aeration.Ahmad JohariAmir MansourizadehDariush EmadzadehWater and Wastewater Consulting Engineers Research Developmentarticleblend hollow fiber membranepolyamide imidesulfonated poly (ether ether ketone)membrane bioreactoroily wastewater treatmentTechnologyTWater supply for domestic and industrial purposesTD201-500Sewage collection and disposal systems. SewerageTD511-780ENFAآب و فاضلاب, Vol 32, Iss 4, Pp 1-20 (2021)
institution DOAJ
collection DOAJ
language EN
FA
topic blend hollow fiber membrane
polyamide imide
sulfonated poly (ether ether ketone)
membrane bioreactor
oily wastewater treatment
Technology
T
Water supply for domestic and industrial purposes
TD201-500
Sewage collection and disposal systems. Sewerage
TD511-780
spellingShingle blend hollow fiber membrane
polyamide imide
sulfonated poly (ether ether ketone)
membrane bioreactor
oily wastewater treatment
Technology
T
Water supply for domestic and industrial purposes
TD201-500
Sewage collection and disposal systems. Sewerage
TD511-780
Ahmad Johari
Amir Mansourizadeh
Dariush Emadzadeh
Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process
description Water pollution with petroleum compounds is one of the most important environmental problems in oil-rich countries, due to its adverse effect on soil, water, and human beings. The hydrophilic hollow fiber membranes were produced by polymer blending of polyamide imide and sulfonated poly ether ether ketone. Membrane structure and function were investigated by field emission scanning electron microscopy analysis, N2 permeation, overall porosity, collapse pressure, water contact angle, pure water flux tests. A membrane bioreactor system was used for oily wastewater treatment. From FESEM, a more open structure with larger finger-like was observed by increasing the PAI / SPEEK ratio. Using the PAI / SPEEK ratio of 85/15, the water contact angle of the membrane was decreased from 74° to 58° which showed a significant hydrophilicity improvement. From compaction test, pure water flux of the membranes showed a gradual decrease during 2.5 h and then reached a steady state with minimal changes. During a period of about 5 hours of the oil separation through the MBR process, the plain PAI membrane and the blend PAI-SPEEK membrane showed water flux reduction of about 35% and 21%, respectively. Under 5 bar transmembrane pressure and the addition of 30 mg/l of oil spill eater (OSEII) enzyme, the oil concentration decreased from 36 ppm to 1.2 ppm in the wastewater, which represents the oil removal efficiency of about 97%. In this work, the optimum state for oil removal was obtained in terms of adding OSEII and aeration.
format article
author Ahmad Johari
Amir Mansourizadeh
Dariush Emadzadeh
author_facet Ahmad Johari
Amir Mansourizadeh
Dariush Emadzadeh
author_sort Ahmad Johari
title Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process
title_short Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process
title_full Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process
title_fullStr Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process
title_full_unstemmed Modification and Enhancement of Hydrophilicity of Hollow Fiber Polymer Alloy Membranes with Sulfonated Poly (Ether Ether Ketone) for the Treatment of Oil Effluents Using the Membrane Bioreactor Process
title_sort modification and enhancement of hydrophilicity of hollow fiber polymer alloy membranes with sulfonated poly (ether ether ketone) for the treatment of oil effluents using the membrane bioreactor process
publisher Water and Wastewater Consulting Engineers Research Development
publishDate 2021
url https://doaj.org/article/82bc1f8facc145c2aee431c4856e1058
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AT amirmansourizadeh modificationandenhancementofhydrophilicityofhollowfiberpolymeralloymembraneswithsulfonatedpolyetheretherketoneforthetreatmentofoileffluentsusingthemembranebioreactorprocess
AT dariushemadzadeh modificationandenhancementofhydrophilicityofhollowfiberpolymeralloymembraneswithsulfonatedpolyetheretherketoneforthetreatmentofoileffluentsusingthemembranebioreactorprocess
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