Convenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of N-methylamines

Convenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of N-methylamines

N-methylated amines display high biological activity in living organisms. Here, the authors show the convenient synthesis of a wide range of biologically relevant N-methylamines via reduction of nitrobenzenes using a recyclable iron catalyst and paraformaldehyde without additional hydrogen pressure.

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Autores principales: Kishore Natte, Helfried Neumann, Rajenahally V. Jagadeesh, Matthias Beller
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/8318295162d94955a313259e9914ae68
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spelling oai:doaj.org-article:8318295162d94955a313259e9914ae682021-12-02T14:40:55ZConvenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of N-methylamines10.1038/s41467-017-01428-02041-1723https://doaj.org/article/8318295162d94955a313259e9914ae682017-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01428-0https://doaj.org/toc/2041-1723N-methylated amines display high biological activity in living organisms. Here, the authors show the convenient synthesis of a wide range of biologically relevant N-methylamines via reduction of nitrobenzenes using a recyclable iron catalyst and paraformaldehyde without additional hydrogen pressure.Kishore NatteHelfried NeumannRajenahally V. JagadeeshMatthias BellerNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-9 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Kishore Natte
Helfried Neumann
Rajenahally V. Jagadeesh
Matthias Beller
Convenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of N-methylamines
description N-methylated amines display high biological activity in living organisms. Here, the authors show the convenient synthesis of a wide range of biologically relevant N-methylamines via reduction of nitrobenzenes using a recyclable iron catalyst and paraformaldehyde without additional hydrogen pressure.
format article
author Kishore Natte
Helfried Neumann
Rajenahally V. Jagadeesh
Matthias Beller
author_facet Kishore Natte
Helfried Neumann
Rajenahally V. Jagadeesh
Matthias Beller
author_sort Kishore Natte
title Convenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of N-methylamines
title_short Convenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of N-methylamines
title_full Convenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of N-methylamines
title_fullStr Convenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of N-methylamines
title_full_unstemmed Convenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of N-methylamines
title_sort convenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of n-methylamines
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/8318295162d94955a313259e9914ae68
work_keys_str_mv AT kishorenatte convenientironcatalyzedreductiveaminationswithouthydrogenforselectivesynthesisofnmethylamines
AT helfriedneumann convenientironcatalyzedreductiveaminationswithouthydrogenforselectivesynthesisofnmethylamines
AT rajenahallyvjagadeesh convenientironcatalyzedreductiveaminationswithouthydrogenforselectivesynthesisofnmethylamines
AT matthiasbeller convenientironcatalyzedreductiveaminationswithouthydrogenforselectivesynthesisofnmethylamines
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