Li@C60 as a multi-state molecular switch

Molecular switches that can access more than just a few states are difficult to realize. Here, the authors use scanning tunnelling microscopy and spectroscopy to show that a surface-bound Li@C60 endofullerene can be switched between 14 molecular states—distinguished by the location of the Li atom in...

Full description

Saved in:
Bibliographic Details
Main Authors: Henry J. Chandler, Minas Stefanou, Eleanor E. B. Campbell, Renald Schaub
Format: article
Language:EN
Published: Nature Portfolio 2019
Subjects:
Q
Online Access:https://doaj.org/article/83372a5e76514904b3e811b4e05a68b1
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Molecular switches that can access more than just a few states are difficult to realize. Here, the authors use scanning tunnelling microscopy and spectroscopy to show that a surface-bound Li@C60 endofullerene can be switched between 14 molecular states—distinguished by the location of the Li atom inside the fullerene cage—by resonant tunnelling through the superatom molecular orbitals.