Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material
Controlling mechanical motions in solid state devices is highly desirable for the development of nanoscale machines. Here, Kepert and colleagues exploit an ultra-flexible coordination framework in which thermally-controlled Fe(II) spin transitions result in remarkable flexing of the crystal lattice.
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Nature Portfolio
2017
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oai:doaj.org-article:835794cf3e9a4c55b3909ad5af32ce2a2021-12-02T17:01:17ZSpin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material10.1038/s41467-017-00776-12041-1723https://doaj.org/article/835794cf3e9a4c55b3909ad5af32ce2a2017-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00776-1https://doaj.org/toc/2041-1723Controlling mechanical motions in solid state devices is highly desirable for the development of nanoscale machines. Here, Kepert and colleagues exploit an ultra-flexible coordination framework in which thermally-controlled Fe(II) spin transitions result in remarkable flexing of the crystal lattice.Benjamin R. MullaneyLaurence Goux-CapesDavid J. PriceGuillaume ChastanetJean-François LétardCameron J. KepertNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-6 (2017) |
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DOAJ |
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Science Q |
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Science Q Benjamin R. Mullaney Laurence Goux-Capes David J. Price Guillaume Chastanet Jean-François Létard Cameron J. Kepert Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material |
description |
Controlling mechanical motions in solid state devices is highly desirable for the development of nanoscale machines. Here, Kepert and colleagues exploit an ultra-flexible coordination framework in which thermally-controlled Fe(II) spin transitions result in remarkable flexing of the crystal lattice. |
format |
article |
author |
Benjamin R. Mullaney Laurence Goux-Capes David J. Price Guillaume Chastanet Jean-François Létard Cameron J. Kepert |
author_facet |
Benjamin R. Mullaney Laurence Goux-Capes David J. Price Guillaume Chastanet Jean-François Létard Cameron J. Kepert |
author_sort |
Benjamin R. Mullaney |
title |
Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material |
title_short |
Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material |
title_full |
Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material |
title_fullStr |
Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material |
title_full_unstemmed |
Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material |
title_sort |
spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/835794cf3e9a4c55b3909ad5af32ce2a |
work_keys_str_mv |
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