Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material

Controlling mechanical motions in solid state devices is highly desirable for the development of nanoscale machines. Here, Kepert and colleagues exploit an ultra-flexible coordination framework in which thermally-controlled Fe(II) spin transitions result in remarkable flexing of the crystal lattice.

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Autores principales: Benjamin R. Mullaney, Laurence Goux-Capes, David J. Price, Guillaume Chastanet, Jean-François Létard, Cameron J. Kepert
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/835794cf3e9a4c55b3909ad5af32ce2a
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