Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material
Controlling mechanical motions in solid state devices is highly desirable for the development of nanoscale machines. Here, Kepert and colleagues exploit an ultra-flexible coordination framework in which thermally-controlled Fe(II) spin transitions result in remarkable flexing of the crystal lattice.
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Auteurs principaux: | Benjamin R. Mullaney, Laurence Goux-Capes, David J. Price, Guillaume Chastanet, Jean-François Létard, Cameron J. Kepert |
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Format: | article |
Langue: | EN |
Publié: |
Nature Portfolio
2017
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Sujets: | |
Accès en ligne: | https://doaj.org/article/835794cf3e9a4c55b3909ad5af32ce2a |
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