Electrooxidative para-selective C–H/N–H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives
Oxidative C–H/N–H cross-coupling is a convenient method to construct C–N bonds, however this is rarely achieved in a sustainable manner. Here, the authors show an oxidant-free electrochemical C–H/N–H cross-coupling between electron-rich arenes and diarylamines to afford triarylamines with exclusive...
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| Autores principales: | , , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2019
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/845623ba04374f65ae0683ba86ebbd18 |
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| Sumario: | Oxidative C–H/N–H cross-coupling is a convenient method to construct C–N bonds, however this is rarely achieved in a sustainable manner. Here, the authors show an oxidant-free electrochemical C–H/N–H cross-coupling between electron-rich arenes and diarylamines to afford triarylamines with exclusive para-selectivity. |
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