Electrooxidative para-selective C–H/N–H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives

Oxidative C–H/N–H cross-coupling is a convenient method to construct C–N bonds, however this is rarely achieved in a sustainable manner. Here, the authors show an oxidant-free electrochemical C–H/N–H cross-coupling between electron-rich arenes and diarylamines to afford triarylamines with exclusive...

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Autores principales:	Kun Liu, Shan Tang, Ting Wu, Shengchun Wang, Minzhu Zou, Hengjiang Cong, Aiwen Lei
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/845623ba04374f65ae0683ba86ebbd18
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spelling	oai:doaj.org-article:845623ba04374f65ae0683ba86ebbd182021-12-02T15:36:17ZElectrooxidative para-selective C–H/N–H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives10.1038/s41467-019-08414-82041-1723https://doaj.org/article/845623ba04374f65ae0683ba86ebbd182019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08414-8https://doaj.org/toc/2041-1723Oxidative C–H/N–H cross-coupling is a convenient method to construct C–N bonds, however this is rarely achieved in a sustainable manner. Here, the authors show an oxidant-free electrochemical C–H/N–H cross-coupling between electron-rich arenes and diarylamines to afford triarylamines with exclusive para-selectivity.Kun LiuShan TangTing WuShengchun WangMinzhu ZouHengjiang CongAiwen LeiNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Kun Liu Shan Tang Ting Wu Shengchun Wang Minzhu Zou Hengjiang Cong Aiwen Lei Electrooxidative para-selective C–H/N–H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives
description	Oxidative C–H/N–H cross-coupling is a convenient method to construct C–N bonds, however this is rarely achieved in a sustainable manner. Here, the authors show an oxidant-free electrochemical C–H/N–H cross-coupling between electron-rich arenes and diarylamines to afford triarylamines with exclusive para-selectivity.
format	article
author	Kun Liu Shan Tang Ting Wu Shengchun Wang Minzhu Zou Hengjiang Cong Aiwen Lei
author_facet	Kun Liu Shan Tang Ting Wu Shengchun Wang Minzhu Zou Hengjiang Cong Aiwen Lei
author_sort	Kun Liu
title	Electrooxidative para-selective C–H/N–H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives
title_short	Electrooxidative para-selective C–H/N–H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives
title_full	Electrooxidative para-selective C–H/N–H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives
title_fullStr	Electrooxidative para-selective C–H/N–H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives
title_full_unstemmed	Electrooxidative para-selective C–H/N–H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives
title_sort	electrooxidative para-selective c–h/n–h cross-coupling with hydrogen evolution to synthesize triarylamine derivatives
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/845623ba04374f65ae0683ba86ebbd18
work_keys_str_mv	AT kunliu electrooxidativeparaselectivechnhcrosscouplingwithhydrogenevolutiontosynthesizetriarylaminederivatives AT shantang electrooxidativeparaselectivechnhcrosscouplingwithhydrogenevolutiontosynthesizetriarylaminederivatives AT tingwu electrooxidativeparaselectivechnhcrosscouplingwithhydrogenevolutiontosynthesizetriarylaminederivatives AT shengchunwang electrooxidativeparaselectivechnhcrosscouplingwithhydrogenevolutiontosynthesizetriarylaminederivatives AT minzhuzou electrooxidativeparaselectivechnhcrosscouplingwithhydrogenevolutiontosynthesizetriarylaminederivatives AT hengjiangcong electrooxidativeparaselectivechnhcrosscouplingwithhydrogenevolutiontosynthesizetriarylaminederivatives AT aiwenlei electrooxidativeparaselectivechnhcrosscouplingwithhydrogenevolutiontosynthesizetriarylaminederivatives
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Electrooxidative para-selective C–H/N–H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives

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