Controllable deuteration of halogenated compounds by photocatalytic D2O splitting

Developing convenient deuterium labeling procedures is important in organic synthesis and the pharmaceutical industry. Here, the authors report a mild photocatalytic strategy for controllable deuteration of halides using D2O as the reagent and porous CdSe nanosheets as the catalyst.

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Detalles Bibliográficos
Autores principales: Cuibo Liu, Zhongxin Chen, Chenliang Su, Xiaoxu Zhao, Qiang Gao, Guo-Hong Ning, Hai Zhu, Wei Tang, Kai Leng, Wei Fu, Bingbing Tian, Xinwen Peng, Jing Li, Qing-Hua Xu, Wu Zhou, Kian Ping Loh
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/84c13466a2614bacbcc0e79cf2f7948c
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Sumario:Developing convenient deuterium labeling procedures is important in organic synthesis and the pharmaceutical industry. Here, the authors report a mild photocatalytic strategy for controllable deuteration of halides using D2O as the reagent and porous CdSe nanosheets as the catalyst.