Synthesis of Some Substituted Furans and Endoperoxides Via Singlet Oxygen Reactions

Cinnamaldehyde was used to condense with substituted acetophenone then with acetone to form substituted 2,4- diene -1- pentanone (1- 4), after two moles of cinnamaldehyde condense with one mole of acetone to form 1, 5- diphenyl nona- 8- tetraene -5 – one (5), for these reactions, sodium hydroxide wa...

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Autores principales:	YASSIR AL-JAWAHERI, Noor M. Mahdi
Formato:	article
Lenguaje:	AR EN
Publicado:	College of Education for Pure Sciences 2021
Materias:	singlet oxygen,, ,،,؛endoperoxide,, ,،,؛furan,, ,،,؛rose bengal catalyst Education L Science (General) Q1-390
Acceso en línea:	https://doaj.org/article/84cb23ed8fa54371b0805433d4ec0b13
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spelling	oai:doaj.org-article:84cb23ed8fa54371b0805433d4ec0b132021-12-01T14:54:26ZSynthesis of Some Substituted Furans and Endoperoxides Via Singlet Oxygen Reactions1812-125X2664-253010.33899/edusj.2021.131010.1183https://doaj.org/article/84cb23ed8fa54371b0805433d4ec0b132021-12-01T00:00:00Zhttps://edusj.mosuljournals.com/article_169742_e9ac877d2afaba63acceb46f4541bda3.pdfhttps://doaj.org/toc/1812-125Xhttps://doaj.org/toc/2664-2530Cinnamaldehyde was used to condense with substituted acetophenone then with acetone to form substituted 2,4- diene -1- pentanone (1- 4), after two moles of cinnamaldehyde condense with one mole of acetone to form 1, 5- diphenyl nona- 8- tetraene -5 – one (5), for these reactions, sodium hydroxide was used as a catalyst, the resulted compounds reduced by Luche (specific reduction agent use cerium chloride as a catalyst with sodium borohydride to protect double bond) reaction to form 2,4- diene-1- methoxy pentane (6-9) and -5- methoxy nona- 1,3,6,8 – tetraene – 1,9 - diyl dibenzene (10), the resulted dienes compound converted to endoperoxides (11- 15) via singlet oxygen reaction in the present of Rose Bengal as a catalyst with light in chlorinated solvent and finally by appling of Appel reaction condition these compounds converted to furans (16- 20). All mechanisms of the reaction were listed. These compounds were identified by thin layer chromatography TLC, and by their physical properties in addition, the IR spectroscopy and 1HNMR.YASSIR AL-JAWAHERINoor M. MahdiCollege of Education for Pure Sciencesarticlesinglet oxygen,,,،,؛endoperoxide,,,،,؛furan,,,،,؛rose bengal catalystEducationLScience (General)Q1-390ARENمجلة التربية والعلم, Vol 30, Iss 5, Pp 147-162 (2021)
institution	DOAJ
collection	DOAJ
language	AR EN
topic	singlet oxygen,, ,،,؛endoperoxide,, ,،,؛furan,, ,،,؛rose bengal catalyst Education L Science (General) Q1-390
spellingShingle	singlet oxygen,, ,،,؛endoperoxide,, ,،,؛furan,, ,،,؛rose bengal catalyst Education L Science (General) Q1-390 YASSIR AL-JAWAHERI Noor M. Mahdi Synthesis of Some Substituted Furans and Endoperoxides Via Singlet Oxygen Reactions
description	Cinnamaldehyde was used to condense with substituted acetophenone then with acetone to form substituted 2,4- diene -1- pentanone (1- 4), after two moles of cinnamaldehyde condense with one mole of acetone to form 1, 5- diphenyl nona- 8- tetraene -5 – one (5), for these reactions, sodium hydroxide was used as a catalyst, the resulted compounds reduced by Luche (specific reduction agent use cerium chloride as a catalyst with sodium borohydride to protect double bond) reaction to form 2,4- diene-1- methoxy pentane (6-9) and -5- methoxy nona- 1,3,6,8 – tetraene – 1,9 - diyl dibenzene (10), the resulted dienes compound converted to endoperoxides (11- 15) via singlet oxygen reaction in the present of Rose Bengal as a catalyst with light in chlorinated solvent and finally by appling of Appel reaction condition these compounds converted to furans (16- 20). All mechanisms of the reaction were listed. These compounds were identified by thin layer chromatography TLC, and by their physical properties in addition, the IR spectroscopy and 1HNMR.
format	article
author	YASSIR AL-JAWAHERI Noor M. Mahdi
author_facet	YASSIR AL-JAWAHERI Noor M. Mahdi
author_sort	YASSIR AL-JAWAHERI
title	Synthesis of Some Substituted Furans and Endoperoxides Via Singlet Oxygen Reactions
title_short	Synthesis of Some Substituted Furans and Endoperoxides Via Singlet Oxygen Reactions
title_full	Synthesis of Some Substituted Furans and Endoperoxides Via Singlet Oxygen Reactions
title_fullStr	Synthesis of Some Substituted Furans and Endoperoxides Via Singlet Oxygen Reactions
title_full_unstemmed	Synthesis of Some Substituted Furans and Endoperoxides Via Singlet Oxygen Reactions
title_sort	synthesis of some substituted furans and endoperoxides via singlet oxygen reactions
publisher	College of Education for Pure Sciences
publishDate	2021
url	https://doaj.org/article/84cb23ed8fa54371b0805433d4ec0b13
work_keys_str_mv	AT yassiraljawaheri synthesisofsomesubstitutedfuransandendoperoxidesviasingletoxygenreactions AT noormmahdi synthesisofsomesubstitutedfuransandendoperoxidesviasingletoxygenreactions
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Synthesis of Some Substituted Furans and Endoperoxides Via Singlet Oxygen Reactions

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