Synthesis and polymerization of 2-(1-methylbut-2-en-1-yl)aniline and its products modification

This work is focused on modifying aniline monomers with various characteristics that allows one to study the effect of the substituent on the respective polymer. A series of new polyaniline (PANI) derivatives based on an ortho-substituted aniline derivative, 2-(1-methylbut-2-en-1-yl)aniline, were sy...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Akhat G. Mustafin, Lyaysan R. Latypova, Anastasiia N. Andriianova
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Polyaniline Poly(ortho-alkylaniline) Solubility Fluorescence Polymer films Sensors Polymers and polymer manufacture TP1080-1185
Acceso en línea:	https://doaj.org/article/84d2a600e9f64438865b01525f47d497
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:84d2a600e9f64438865b01525f47d497
record_format	dspace
spelling	oai:doaj.org-article:84d2a600e9f64438865b01525f47d4972021-11-14T04:27:43ZSynthesis and polymerization of 2-(1-methylbut-2-en-1-yl)aniline and its products modification0142-941810.1016/j.polymertesting.2021.107351https://doaj.org/article/84d2a600e9f64438865b01525f47d4972021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S0142941821002968https://doaj.org/toc/0142-9418This work is focused on modifying aniline monomers with various characteristics that allows one to study the effect of the substituent on the respective polymer. A series of new polyaniline (PANI) derivatives based on an ortho-substituted aniline derivative, 2-(1-methylbut-2-en-1-yl)aniline, were synthesized and characterized. The structures and composition of the polymers that we synthesized were confirmed by elemental analysis, proton nuclear magnetic resonance (1H NMR) spectroscopy, carbon nuclear magnetic resonance (13C NMR) spectroscopy, Fourier-transform infrared spectroscopy (FT-IR), and ultraviolet–visible spectroscopy (UV). Characterization by FT-IR and UV–visible spectroscopy techniques indicated that the polymers exist in protonated emeraldine forms. The polymers are soluble in common organic solvents, so they can be used to make films. It was shown the prospect of using thin polymer films in the design of chemical sensors. The impact of the substituent on the polymer characteristics is rationalized in terms of steric and electronic effects.Akhat G. MustafinLyaysan R. LatypovaAnastasiia N. AndriianovaElsevierarticlePolyanilinePoly(ortho-alkylaniline)SolubilityFluorescencePolymer filmsSensorsPolymers and polymer manufactureTP1080-1185ENPolymer Testing, Vol 104, Iss , Pp 107351- (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Polyaniline Poly(ortho-alkylaniline) Solubility Fluorescence Polymer films Sensors Polymers and polymer manufacture TP1080-1185
spellingShingle	Polyaniline Poly(ortho-alkylaniline) Solubility Fluorescence Polymer films Sensors Polymers and polymer manufacture TP1080-1185 Akhat G. Mustafin Lyaysan R. Latypova Anastasiia N. Andriianova Synthesis and polymerization of 2-(1-methylbut-2-en-1-yl)aniline and its products modification
description	This work is focused on modifying aniline monomers with various characteristics that allows one to study the effect of the substituent on the respective polymer. A series of new polyaniline (PANI) derivatives based on an ortho-substituted aniline derivative, 2-(1-methylbut-2-en-1-yl)aniline, were synthesized and characterized. The structures and composition of the polymers that we synthesized were confirmed by elemental analysis, proton nuclear magnetic resonance (1H NMR) spectroscopy, carbon nuclear magnetic resonance (13C NMR) spectroscopy, Fourier-transform infrared spectroscopy (FT-IR), and ultraviolet–visible spectroscopy (UV). Characterization by FT-IR and UV–visible spectroscopy techniques indicated that the polymers exist in protonated emeraldine forms. The polymers are soluble in common organic solvents, so they can be used to make films. It was shown the prospect of using thin polymer films in the design of chemical sensors. The impact of the substituent on the polymer characteristics is rationalized in terms of steric and electronic effects.
format	article
author	Akhat G. Mustafin Lyaysan R. Latypova Anastasiia N. Andriianova
author_facet	Akhat G. Mustafin Lyaysan R. Latypova Anastasiia N. Andriianova
author_sort	Akhat G. Mustafin
title	Synthesis and polymerization of 2-(1-methylbut-2-en-1-yl)aniline and its products modification
title_short	Synthesis and polymerization of 2-(1-methylbut-2-en-1-yl)aniline and its products modification
title_full	Synthesis and polymerization of 2-(1-methylbut-2-en-1-yl)aniline and its products modification
title_fullStr	Synthesis and polymerization of 2-(1-methylbut-2-en-1-yl)aniline and its products modification
title_full_unstemmed	Synthesis and polymerization of 2-(1-methylbut-2-en-1-yl)aniline and its products modification
title_sort	synthesis and polymerization of 2-(1-methylbut-2-en-1-yl)aniline and its products modification
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/84d2a600e9f64438865b01525f47d497
work_keys_str_mv	AT akhatgmustafin synthesisandpolymerizationof21methylbut2en1ylanilineanditsproductsmodification AT lyaysanrlatypova synthesisandpolymerizationof21methylbut2en1ylanilineanditsproductsmodification AT anastasiianandriianova synthesisandpolymerizationof21methylbut2en1ylanilineanditsproductsmodification
_version_	1718430024691875840

Synthesis and polymerization of 2-(1-methylbut-2-en-1-yl)aniline and its products modification

Ejemplares similares