Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis

Stabilization of covalent organic frameworks (COFs) by post-synthetic locking is a powerful tool to push the limits of COF utilization. Here the authors demonstrate a sulfur-assisted conversion of an imine-linked COF into a thiazole-linked COF, with retention of crystallinity and porosity, allowing...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Frederik Haase, Erik Troschke, Gökcen Savasci, Tanmay Banerjee, Viola Duppel, Susanne Dörfler, Martin M. J. Grundei, Asbjörn M. Burow, Christian Ochsenfeld, Stefan Kaskel, Bettina V. Lotsch
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
Materias:
Q
Acceso en línea:https://doaj.org/article/84db9441b03b489aa5f82d3b804c4278
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:84db9441b03b489aa5f82d3b804c4278
record_format dspace
spelling oai:doaj.org-article:84db9441b03b489aa5f82d3b804c42782021-12-02T17:33:17ZTopochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis10.1038/s41467-018-04979-y2041-1723https://doaj.org/article/84db9441b03b489aa5f82d3b804c42782018-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04979-yhttps://doaj.org/toc/2041-1723Stabilization of covalent organic frameworks (COFs) by post-synthetic locking is a powerful tool to push the limits of COF utilization. Here the authors demonstrate a sulfur-assisted conversion of an imine-linked COF into a thiazole-linked COF, with retention of crystallinity and porosity, allowing for direct imaging of defects in COFs.Frederik HaaseErik TroschkeGökcen SavasciTanmay BanerjeeViola DuppelSusanne DörflerMartin M. J. GrundeiAsbjörn M. BurowChristian OchsenfeldStefan KaskelBettina V. LotschNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Frederik Haase
Erik Troschke
Gökcen Savasci
Tanmay Banerjee
Viola Duppel
Susanne Dörfler
Martin M. J. Grundei
Asbjörn M. Burow
Christian Ochsenfeld
Stefan Kaskel
Bettina V. Lotsch
Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis
description Stabilization of covalent organic frameworks (COFs) by post-synthetic locking is a powerful tool to push the limits of COF utilization. Here the authors demonstrate a sulfur-assisted conversion of an imine-linked COF into a thiazole-linked COF, with retention of crystallinity and porosity, allowing for direct imaging of defects in COFs.
format article
author Frederik Haase
Erik Troschke
Gökcen Savasci
Tanmay Banerjee
Viola Duppel
Susanne Dörfler
Martin M. J. Grundei
Asbjörn M. Burow
Christian Ochsenfeld
Stefan Kaskel
Bettina V. Lotsch
author_facet Frederik Haase
Erik Troschke
Gökcen Savasci
Tanmay Banerjee
Viola Duppel
Susanne Dörfler
Martin M. J. Grundei
Asbjörn M. Burow
Christian Ochsenfeld
Stefan Kaskel
Bettina V. Lotsch
author_sort Frederik Haase
title Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis
title_short Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis
title_full Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis
title_fullStr Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis
title_full_unstemmed Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis
title_sort topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/84db9441b03b489aa5f82d3b804c4278
work_keys_str_mv AT frederikhaase topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
AT eriktroschke topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
AT gokcensavasci topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
AT tanmaybanerjee topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
AT violaduppel topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
AT susannedorfler topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
AT martinmjgrundei topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
AT asbjornmburow topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
AT christianochsenfeld topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
AT stefankaskel topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
AT bettinavlotsch topochemicalconversionofanimineintoathiazolelinkedcovalentorganicframeworkenablingrealstructureanalysis
_version_ 1718380010395402240