Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis
Stabilization of covalent organic frameworks (COFs) by post-synthetic locking is a powerful tool to push the limits of COF utilization. Here the authors demonstrate a sulfur-assisted conversion of an imine-linked COF into a thiazole-linked COF, with retention of crystallinity and porosity, allowing...
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Nature Portfolio
2018
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oai:doaj.org-article:84db9441b03b489aa5f82d3b804c42782021-12-02T17:33:17ZTopochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis10.1038/s41467-018-04979-y2041-1723https://doaj.org/article/84db9441b03b489aa5f82d3b804c42782018-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04979-yhttps://doaj.org/toc/2041-1723Stabilization of covalent organic frameworks (COFs) by post-synthetic locking is a powerful tool to push the limits of COF utilization. Here the authors demonstrate a sulfur-assisted conversion of an imine-linked COF into a thiazole-linked COF, with retention of crystallinity and porosity, allowing for direct imaging of defects in COFs.Frederik HaaseErik TroschkeGökcen SavasciTanmay BanerjeeViola DuppelSusanne DörflerMartin M. J. GrundeiAsbjörn M. BurowChristian OchsenfeldStefan KaskelBettina V. LotschNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018) |
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Science Q |
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Science Q Frederik Haase Erik Troschke Gökcen Savasci Tanmay Banerjee Viola Duppel Susanne Dörfler Martin M. J. Grundei Asbjörn M. Burow Christian Ochsenfeld Stefan Kaskel Bettina V. Lotsch Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis |
description |
Stabilization of covalent organic frameworks (COFs) by post-synthetic locking is a powerful tool to push the limits of COF utilization. Here the authors demonstrate a sulfur-assisted conversion of an imine-linked COF into a thiazole-linked COF, with retention of crystallinity and porosity, allowing for direct imaging of defects in COFs. |
format |
article |
author |
Frederik Haase Erik Troschke Gökcen Savasci Tanmay Banerjee Viola Duppel Susanne Dörfler Martin M. J. Grundei Asbjörn M. Burow Christian Ochsenfeld Stefan Kaskel Bettina V. Lotsch |
author_facet |
Frederik Haase Erik Troschke Gökcen Savasci Tanmay Banerjee Viola Duppel Susanne Dörfler Martin M. J. Grundei Asbjörn M. Burow Christian Ochsenfeld Stefan Kaskel Bettina V. Lotsch |
author_sort |
Frederik Haase |
title |
Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis |
title_short |
Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis |
title_full |
Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis |
title_fullStr |
Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis |
title_full_unstemmed |
Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis |
title_sort |
topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/84db9441b03b489aa5f82d3b804c4278 |
work_keys_str_mv |
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1718380010395402240 |